不同pH值下腐殖酸反渗透膜污染中的界面相互作用解析.PDFVIP

中国环境科学 2011,31(4) ：616~621 China Environmental Science 不同 pH 值下腐殖酸反渗透膜污染中的界面相互作用解析 彭 茜,冉德钦,王 平,殷永泉,梁 爽* ( 山东大学环境科学与工程学院, 山东 济南 250100) 摘要：应用 extended derjaguin-landau-verwey-overbeek (扩展 DLVO) 理论评价不同 pH 值下范德华力、静电力、疏水性力 3 种界面相互作 用对腐殖酸反渗透(reverse osmosis, RO)膜污染的贡献,探究 pH 值影响腐殖酸 RO 膜污染的主控机制.对 3 种常规 RO 膜的理论分析结果表 明,静电力对腐殖酸RO 膜污染的贡献很小,范德华力使膜污染加剧;疏水性力会减缓膜污染.与前期粘附阶段相比,后期粘聚阶段中范德华力 的贡献有所增大,疏水性力在 2 个污染阶段中均起主导作用.膜污染随 pH 值的降低而加重,疏水性力作用能的改变是 pH 值影响系统界面自 由能的主控机制.相应 pH 值下 3 种 RO 膜过滤实验数据及其相关性分析结果表明,扩展 DLVO 理论能定量评价 3 种界面相互作用的贡献, 界面自由能和膜污染之间有很好的相关关系,RO 膜纯水接触角的数值不宜作为评价膜污染的指标. 关键词：反渗透膜；腐殖酸；膜污染；界面自由能；扩展 DLVO 理论 中图分类号：X131.2 文献标识码：A 文章编号：1000-6923(2011)04-0616-06 Analysis of interfacial interactions in reverse osmosis membrane fouling by humic acid Effect of solution pH. * PENG Qian, RAN De-qin, WANG Ping, YIN Yong-quan, LIANG Shuang (School of Environmental Science and Engineering, Shandong University, Jinan 250100, China). China Environmental Science, 2011,31(4)：616~621 Abstract ：The extended Derjaguin-Landau-Verwey-Overbeek (XDLVO) approach was applied for better understanding of the basic interfacial interactions (i.e. van der Waals interaction, electrostatic interaction and acid-base interaction) involved in reverse osmosis(RO)membrane fouling by humic acid at different pHs. Based on the theoretical calculations with three representative RO membranes, the electrostatic interaction was found to be negeligible in membrane fouling. The van der Waals interaction favored fouling, whereas acid-base interaction could prevent it. The contribution of van der Waals interaction was higher in the cohesion stage than that in the adhesion stage. The acid-base interaction was dominant in both stages. Membrane fouling became less serious as so