高温高浓竹浆黑液流变性及膨胀性研究.docVIP

高温高浓竹浆黑液流变性及膨胀性研究 岳小鹏 杜鑫 徐永建 陕西科技大学陕西省造纸技术及特种纸品开发重点实验室 陕西科技大学机电工程学院 X 关注成功！ 加关注后您将方便地在 我的关注中得到本文献的被引频次变化的通知！ 新浪微博 腾讯微博 人人网 开心网 豆瓣网 网易微博 摘????要： 碱回收蒸发系统新技术的应用, 使入炉黑液固含量超过70%, 因此有必要研究高固含量黑液的流变性能.NaAlO2在燃烧法除硅工艺中除硅效果极佳, 需要探究其对竹浆黑液膨胀性带来的影响.本文利用AR2000ex动态流变仪, 在70℃和98℃高温条件下对固含量为70.19%和79.87%的竹浆黑液的流变特性进行研究, 发现在0100s-1剪切速率范围内竹浆黑液符合假塑性流体的流动特征, 且呈现出较强的弹性固体性质.提高温度可以有效降低黑液的表观粘度, 减弱黑液的假塑性, 削弱其内部结构强度, 有助于黑液在碱回收过程中的输送.通过对黑液等温膨胀体积指数 (VIE) 的测定, 发现NaAlO2添加量为0.5%时, 黑液的膨胀率最大, 继续加大添加量会抑制黑液的膨胀. 关键词： 黑液; 流变特性; 假塑性; 膨胀性; 作者简介：岳小鹏 (1982-) , 男, 山东青岛人, 讲师, 博士, 研究方向:生物质复合材料 作者简介：徐永建 (1970-) , 男, 陕西西安人, 教授, 博士生导师, 研究方向:植物纤维资源高值化利用、清洁生产及碱回收除硅技术, 154197301@ 收稿日期：2017-07-27 基金：国家十二五科技支撑计划项目 (2012BAD23B02) Study on rheological properties and expansion of thick bamboo kraft black liquor at high temperature YUE Xiao-peng DU Xin XU Yong-jian Shaanxi Province Key Laboratory of Papermaking Technology and Specialty Paper, Shaanxi University of Science Technology; Abstract： It is necessary to study the rheological properties of black liquor at a high solid content above 70 wt% due to the development of new technology for the recovery unit in pulp and paper industry.Adding sodium aluminate can ensure high efficiency in the method of black liquor combustion to remove silicon.Nevertheless, the effect of sodium aluminate on the expansion of black liquor should not be ignored.The rheological properties of thick bamboo kraft black liquor (70.19 wt% and 79.87 wt%) at different temperatures (70 ℃ and 98 ℃) were investigated by an AR2000ex rotational rheometer.The results proved that the flowability of the bamboo kraft black liquor obeyed the law of pseudoplastic fluid in the shear rate range of 0100 s-1.Thick bamboo kraft black liquor represented strong elastic solid properties.The apparent viscosity of black liquor could be reduced effectively with the increase of temperature.High temperature also weakened the pseudoplastic characteristics of black liquor, as well as the intensity of the molecul