耐高温有机硅树脂的合成_贾梦秋.pdfVIP

35 7 V ol1 35 N o1 7 2007 7 N EW CH EM ICAL MA TERIA L S # 4 6# ( , 100029) , 2 , , , 65e , 4~ 5h , ( IR) , , , ( GPC) , 6500 ( T G) , , 500 e 71 12% , 300 e , , , , Synthesis of heat2resistant silicone resin Jia Mengqiu Deng H aifen g ( College of Mat er ials Scien ce an d En gin eerin g, Beijin g Un iversit y of Chemical T echnology, Beij ing 100029) Abstr act Th e silicon e resin was synth esized w ith t he hy dr olysis2p olycon den sation meth od f rom alk oxysilan es, an d th e influ en ce of th e synth esizing process on th e propert y of th e silicon e r esin was also investigat ed. Th e result s in dicat ed th at silicone r esin can been synthesized w ell wh en the hydr oly sis t emper ature was 65 e and th e hy dr olysis time w as 4~ 5h usin g a cer t ain synth esizing r ecip e th e IR an aly sis sh ow ed th at t he synth esized silicon e resin w as en ded by hydroxyl group , aft er adding S2i N oligomer , it cou ld been cured at room t emp er ature GPC an alysis rev ealed th at th e average molecular weight of th e r esin w as aroun d 6500 g # mol- 1 TG an aly sis showed th at t he resin h ad excellent th ermal st ab ility , an d it s mass loss was on ly 71 12% at 500e Th e mech an ical an d EIS an alysis proved th at th e mechan ical pr op erty an d imper mea2 b ility wer e both ex cellent at 300 e , wh ich pr edict ed a good app lication in h eat2resist ant coating s. Key words silicon e resin , alkoxy silan e, curing at room t emp erature , , , [1] ,