TiO2PS核壳型微球和空心TiO2微球有序排列的制备研究.pdfVIP

TiO /PS 核壳型微球和空心TiO 微球有序排列的制备 2 2 周倩，董鹏 （中国石油大学重质油国家重点实验室，北京 102249 ） 摘要：利用纳米级二氧化钛（TiO2 ）溶胶微粒与聚苯乙烯（PS ）胶体颗粒的混合悬浮液，以垂直 共沉积的方法制备了核壳型TiO2/PS 微球的有序排列。当利用煅烧的方法去除PS 胶粒晶体模板 后，可以形成空心TiO2 微球的三维有序排列。考察了混合悬浮液中两种胶体颗粒的体积比（PS ： TiO2 ＝R ）对空心TiO2 微球有序排列形成的影响。实验结果表明，合适的R （6:1 ）对于空心微球 有序排列的形成至关重要。与此同时，浸渍填充法对照实验的结果表明，煅烧过程中 TiO2 纳米 颗粒晶型转化引起的收缩是造成TiO2 空心球产生的主要原因。 关键词：空心TiO2 微球; 胶体颗粒; 有序排列 中图分类号：TQ050.4+3 文献标识码：A Preparation for ordered arrays of PS/TiO core-shell microspheres 2 and hollow TiO2 microspheres ZHOU Qian ，DONG Peng (State Key Laboratory of Heavy Oil Processing, University of Petroleum, Beijing 102249) Abstract: The ordered arrays of titanium dioxide (TiO ) and polystyrene (PS) core-shell 2 microspheres were prepared by using vertical co-deposition method and composite suspensions of TiO2 colloidal particles with nanometer size and polystyrene (PS) colloidal particles with submicron size. By this way, the preparation and assembly of core-shell microspheres could be realized synchronously. This kind ordered arrays of core-shell microspheres had many special optical properties, such as they may generate a complete band-gap. After removing the PS colloidal crystal template, ordered arrays of hollow TiO2 microspheres were formed. The effect of the volume ratio (R) of PS to TiO2 colloidal particles on the formation of ordered arrays was in