5-3-2.周环反应.pptVIP

Woodward 的发现 Woodward 的发现 Electrocyclic Reactions 热反应 光反应 * * * * * ?2009 Shu-peng Zhang Nanjing University of Science Technology All Rights Reserved Pericyclic Reaction Pericyclic Reaction I Two different p bond-containing molecules react to form a cyclic compound Pericyclic Reaction II An intramolecular reaction in which a new s bond is formed between the ends of a conjugated p system Electrocyclic Reactions Are Reversible An electrocyclic reaction is completely stereoselective The configuration of the product formed depends on: the configuration of the reactant the number of conjugated double bonds or pairs of electrons in the reacting system whether the reaction is a thermal or a photochemical reaction A photochemical reaction takes place when a reactant absorbs light A thermal reaction takes place without the absorption of light Conservation of Orbital Symmetry Theory Explains the relationship among the structure and configuration of the reactant, the conditions (thermal or photochemical) under which the reaction takes place, and the configuration of the products States that in-phase orbitals overlap during the course of a pericyclic reaction