可见光下氮掺杂二氧化钛对巯基苯并噻唑的降解 The Photodegradation of 2-mercaptobenzothiazole in the suspension of nitrogen-doped titania under visible light.pdfVIP

生态环境 2006, 15(4): 720-723 Ecology and Environment E-mail: editor@ The Photodegradation of 2-mercaptobenzothiazole in the suspension of nitrogen-doped titania under visible light QIN Haoli 1, 2, GU Guobang 1, LIU Song 1 1. College of Chemistry, South China University of Technology, Guangzhou 510640, China; 2. College of Science, Guizhou Normal University, Guiyang 551000, China Abstract: In order to utilize visible light in photocatalytic reaction, yellow nitrogen-doped titania were prepared by sol-gel method in mild condition, with the elemental nitrogen source from aqua ammonia. The catalysts were characterized by XRD, TEM, XPS, and UV-Vis diffuse reflectance spectrophotometer. The analytical results demonstrated that all catalysts were anatase, and the crystallite size of nitrogen-doped titania increased with increasing of N/Ti proportioning, and the doping of nitrogen could extend the absorption shoulder into the visible light region. With a purpose of odor control, 2-mercaptobenzothiazole (MBT) was used in this study as a model chemical, and photocatalytic activities of the nitrogen-doped titania were investigated based on the MBT photodegradation in aqueous solution under visible light. The experimental results showed that the photocatalytic activity of nitrogen-doped titania were nearly 3 times higher than that of the commercial titania photocatalyst Degussa P-25 for MBT degradation under visible light irradiation. In addition, there was an optimum N/Ti proportioning to exhibit the highest visible-light activity. Key words: titania; 2-mercaptobenzothiazole; nitrogen-doped; visible