离子液体1甲基咪唑硫酸氢盐催化玉米芯制取糠醛的研讨.pdfVIP

离子液体1-甲基咪唑硫酸氢盐催化玉米芯制取糠醛的研究 汪全义 康凯 兰先秋 付超 宋航∗ （四川大学化工学院 成都 610065） 摘要：本文研究了用离子液体 1-甲基咪唑硫酸氢盐[Hmim]HSO (1-Methylimidazolium hydrogen sulfate) 4 代替浓硫酸催化玉米芯制备糠醛，考察了以离子液体[Hmim]HSO 催化玉米芯制取糠醛过程中的主要影响因 4 素，得出较优的反应条件，并对[Hmim]HSO 与浓硫酸催化玉米芯制备糠醛进行了简单的对比。结果表明， 4 离子液体[Hmim]HSO 具有较强的催化能力；产物收率接近污染较严重的浓硫酸作催化剂的结果；能够较显 4 著地减少废水的排放。实验室研究证明，该方法可作为以玉米芯为原料制备糠醛的绿色环保的新工艺路线， 不仅可以减少工业三废的产生，缓解环境污染的问题，实现化工工艺绿色化，而且可以达到物尽其用、变 废为宝，最大限度地的实现经济效益。 关键词：离子液体；糠醛；催化反应 Study on the preparation of furfural from corncob catalyzed by ionic liquid 1-Methylimidazolium hydrogen sulfate Wang Quanyi, kang kai, Lan Xianqiu, Fu Chao, Song Hang* (School of Chemical Industry, Sichuan University, Chengdu, 610065) Abstract:The paper studies the preparation of furfural from corncob catalyzed by the ionic liquid [Hmim]HSO4 (1-Methylimidazolium hydrogen sulfate) in place of concentrated sulfuric acid, investigates the main factors of the reaction, and obtains the better reaction condition, and compares preparing furfural from corncob catalyzed by [Hmim]HSO4 with by concentrated sulfuric acid. The results show that [Hmim]HSO4 has strong catalytic ability; The yield of furfural catalyzed by [Hmim]HSO4 is close to that catalyzed by concentrated sulfuric acid caused serious pollution; The technology can reduce industrial wastes remarkably. Laboratory studies show that the technology can be used as a green new technology courses to prepare furfural from corncob, it can not only reduce the number of industrial waste to anesis environmental pollution and achieve a green chemical process, but also can get the utility of things exha