离子液体水介质中纳米TiO2的合成及其光催化性能研究.pdfVIP

离子液体-水介质中纳米TiO2 的合成及其光催化性能 *1 刘红 , 何世强, 梁玉广 (上海大学化学工程与工艺系, 上海201800) + - 摘要：本文以钛酸四丁酯（TBOT ）为前驱体，通过水热合成法在离子液体BMIM BF4 －水 介质中成功制备出了纳米TiO2 ，通过X 射线粉末衍射（XRD ）、透射电子显微镜（TEM ）、 低温N2 吸附等手段对产物进行表征，并考察了纳米TiO2 在对氯苯酚光降解反应中的催化性 能。结果表明：所合成的 TiO2 全部为锐钛矿，离子液体的加入有利于锐钛矿的形成，提高 TiO2 的热稳定性。光催化降解对氯苯酚表明合成的纳米TiO2 具有优异的催化性能，在250W 紫外灯照射2h 后，对氯苯酚降解率可达96.3%，优于商品P25 催化剂。 关键词：TiO2 ；光催化；对氯苯酚；离子液体；纳米 中图分类号：O643 文献标识码：A Synthesis of nanocrystalline TiO particles in mixture of 2 ionic liquid-water and its photocatalytic performance LIU Hong, HE Shiqiang, LIANG Yuguang (Department of Chemical Engineering, Shanghai University, Shanghai 201800, China) Abstract: The nanocrystalline TiO2 was prepared in mixture solvent of ionic liquid + - (1-butyl-3-methyl-imidazolium tetrafluoroborate, BMIM BF4 ) and water by hydrothermal method using tetrabutyl orthotitanate (TBOT) as basis materials. X-ray diffraction (XRD), trans- mission electron microscope (TEM), and nitrogen adsorption measurement techniques were em- ployed to characterize the final products. The photocatalytic activity of the samples was evaluated by photocatalytic degradation of p -chlorophenol. The results showed that the nanocrystalline TiO2 obtained was antase. In the presence of ionic liquid, highly crystalline titania could be obtained at relatively low temperature and shorter time. The TiO2 particles synthesized in mixture of ionic liquid-water have good thermal stability to resist anatase-to-rutile crystal phase transformation during the