Reinvestigation of the crystal structure of the zeolite go英文资料.pdfVIP

American Mineralogist, Volume 95, pages 481–486, 2010 Reinvestigation of the crystal structure of the zeolite gobbinsite: A single-crystal X-ray diffraction study G. DieGo Gatta,1,2,* William D. Birch,3 anD nicola rotiroti1,2 1Dipartimento di Scienze della Terra, Università degli Studi di Milano, via Botticelli 23, I-20133 Milano, Italy 2CNR-Istituto per la Dinamica dei Processi Ambientali, Milano, Italy 3Geosciences section, Museum Victoria, GPO Box 666, Melbourne, Victoria 3001, Australia aBstract The crystal structure of a natural Na-rich gobbinsite from Bundoora, a northern suburb of Melbourne, Victoria, Australia [(Na K Ca ) (Al Si ) O ·11.91H O, Z = 1, a = 10.1035(15), b = 4.97 0.07 0.48 Σ5.52 5.62 10.29 Σ15.91 32 2 3 9.7819(10), c = 10.1523(9) Å, and V = 1003.37(20) Å , space group Pmnb (no. 62)], has been investi- gated by means of single-crystal X-ray diffraction, elemental CHN analysis, and electron microprobe analysis in the wavelength dispersive mode. For the first time, an anisotropic structural refinement has been performed on the basis of single-crystal X-ray diffraction data collected at 298 K, with: R (F) 1 = 0.0608, 1362 unique reflections with F 4σ(F ), and 114 refined paramete