面向固体热解单一活化能计算的等转化率动力学分析方法研究 New isoconversional method for evaluating unambiguous activation energy values for solid decomposition.pdfVIP
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面向固体热解单一活化能计算的等转化率动力学分析方法研究 New isoconversional method for evaluating unambiguous activation energy values for solid decomposition
第20卷第1期 火 灾 科 学 V01.20,No.1
201 1年1月 011
FIRE Jan.2
SAFETYSCIENCE
文章编号:1004—5309(2011)一0009—07
Newisoconversionalmethodfor
evaluatingunambiguous
activationvaluesforsolid
energy decomposition
HAN Nai~an。
Yun-qing,LIU
ofFire ofScience
(StateKeyLaboratoryScience,UniversityandTechnologyofChina,Hefei,230026,China)
new
Abstract:Aisoconversionalmethodbasedonthemodified methodis toevaluate
Vyazovkin theactivation
proposed energy
forsolid—state
reactions.Thismethodisusedwithout ofreactionmechanismsand the
anypre—knowledge overcomeslimitation
ofcurrentisoconversional
methodsthat failtO activationvalueslike methods.This
they giveunambiguous
energy model—fitting
methodwastestedinboth
ofsimulateddataand dataofextruded showed
experimental polystyrenedecomposition,whichthat
thismethodhad toleranceof noiseandwas tObemoreeffectivethan methods
good experimental proved model—fittingtOextract
reliableactivationvaluesthose
energy reactionswhosefirst—orderderivativeof datatumoutdistinct
multiple thermogravimetric
maximums.
Keyword:Isoeonversional method;Activation
method:Model—fitting energy
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