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11_【2010 J Solid State Electrochem 】LiNiO2@LiCoO2
J Solid State Electrochem (2010) 14:1117– 1124
DOI 10.1007/s10008-009-0927-x
ORIGINAL PAPER
Low temperature synthesis of LiNiO @LiCoO as cathode
2 2
materials for lithium ion batteries
Xian-Zhu Fu Xin Wang Hong-Feng Peng
Fu-Sheng Ke Jun-Hu Lei Ling Huang
Jing-Dong Lin Dai-Wei Liao
Received: 25 March 2009 /Revised: 6 August 2009 /Accepted: 19 August 2009 /Published online: 29 August 2009
# Springer-Verlag 2009
Abstract Spherical LiNiO @LiCoO as cathode material Introduction
2 2
for lithium ion batteries was synthesized by firing the
mixture of β-NiOOH@β-CoOOH and LiOH at low LiNiO2 is one of the most promising cathode materials for
temperature in air atmosphere. The effect of synthesis lithium ion batteries due to its lower cost and higher
conditions on the structure of the resultant samples was capacity in comparison with LiCoO2 which has been
investigated by X-ray diffraction, scanning electron micro- widely utilized in the commercial lithium ion batteries [ 1,
scope, and energy dispersive spectroscope. Spherical 2]. However, some problems of LiNiO2, such as difficult
LiNiO2@LiCoO2 obtained at 600 °C for 24 h exhibited preparation, instability during the charge–discharge cycle,
best layered hexagonal structure and remained core-shell and storage, need to be solved for its commercialization
property. Electrochemical test demonstrated that LiNiO2@- [3].
LiCoO2 had high initial discharge capacity of 181.4 mA h g−1, The traditional synthesis of LiNiO2 is usually use of
better cycle, and s
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