Adsorption and desorption performance of benzene over hierarchically structured carbon–silica aerogel composites英文文献.pdfVIP

Journal of Hazardous Materials 196 (2011) 194–200 Contents lists available at SciVerse ScienceDirect Journal of Hazardous Materials j o u r n a l h o me p a g e: w w w. elsev /locate/jha z mat Adsorption and desorption performance of benzene over hierarchically structured carbon–silica aerogel composites Baojuan Dou, Jinjun Li, Yufei Wang, Hailin Wang, Chunyan Ma ∗ , Zhengping Hao ∗∗ Department of Environmental Nano-Materials, Research Centerfor Eco-Environmental Sciences, Chinese Academy of Sciences, Beijing 100085, PR China a r t i c l e i n f o a b s t r a c t Article history: Hierarchically structured carbon–silica aerogel (CSA) composites were synthesized from cheap water Received 9 March 2011 glass precursors and granulated activated carbon via a post-synthesis surface modification with Received in revised form 2 September 2011 trimethylchlorosilane (TMCS) and a low-cost ambient pressure drying procedure. The resultant CSA com- Accepted 5 September 2011 posites possess micro/mesoporous structure and hydrophobic surface. The adsorption and desorption Available online 10 September 2011 performance of benzene on carbon–silica aerogel composite (CSA-2) under static and dynamic condi- tions were investigated, comparing with pure silica aerogel (CSA-0) and microporous activated carbon Keywords: (AC). It was found that CSA-2 has high affinity towards aromatic molecules and fast adsorptio