无机化学第五章 酸碱平衡与酸碱滴定法.pptVIP

解：HAc + H2O H3O+ + Ac– 0.10-x x x 设 H3O+ 的平衡浓度为 x 则 Ka = [H3O+] [Ac–] / [HAc] = x2 / (0.10-x) ? x2 / 0.10 = 1.75 × 10–5 x = [H3O+] = (0.10 × 1.75 × 10–5 )0.5 = 1.3× 10–3 (mol/L ) 解离度? = x / C0 = 1.3× 10–3 / 0.10 = 0.013 (1.3%) [例]：求0.10 mol/L HAc水溶液的酸度，已知 Ka = 1.75× 10–5 例：（1）25℃，0.1mol/LHAc，求[H+],[Ac-],αHAc. （已知：Ka= 1.75×10-5） 方法1：[H+] = [Ac-] = αHAc=(1.32×10-3/0.1)×100%=1.32% 方法2：∵C/Ka﹥500 （2）将此溶液稀释至0.01mol/