高性能碳纤维水下电场电极制备及其性能测量.docVIP

高性能碳纤维水下电场电极制备及其性 能测量 申振宋玉苏王月明 海军工程大学理学院 对T300碳纤维在445°C、465°C、485°C下进行表面热处理，以获得新型水下电 场电极。利用X射线光电子能谱(XPS)分析、电化学工作站、自制电极响应装 置和电极自噪声测量装置对其在NaCl溶液中的表面化学状态、电化学特性和探 测性能进行了测量，讨论热处理温度对其表面基团含量、循环伏安特性、交换电 流密度、响应性能和电极稳定时间的影响，分析了其电场探测机理。结果表明： 热处理温度的提高可提高碳纤维表面基团C = 0和COOR含量，减小电极在Na C1 溶液中的电容效应，增加电极的交换电流密度，提高电极的线性性能和稳定速 度。 关键词： 兵器科学与技术;水卜‘电场电极;碳纤维;热处理;a噪声;电化学;x射线光 电子能谱； 申振(1989—)，男，研究生。E-mail :dadahuaishuxia@163. com 宋玉苏(1964—)，女，教授，生导师。 E-mail:138711646520139. com 2017-03-22 基金：国家科学自然基金项FI Preparation and Performance Measurement of High Performance Underwater Carbon Fiber Electric Field Electrode SHEN Zhen SONG Yu_su WANG Yue—ming College of Science, Naval University of Engineering; Abstract： A novel underwater electric field electrode is prepared with T300 carbon fiber heat-treated at445 °C, 465 °C and 485 °C. The surface chemical state, electrochemical performance and detection performance of electric field electrode in Na Cl solution are measured using X-ray photoelectron spectroscopy ( XPS) ， electrochemical workstation and self-made noise measurement system. The impact of heat treatment on surface group content, cyclic voltammetry ( CV) characteristics， exchange current density, response performance and electrode settling time is discussed.The detection mechanism of underwater carbon fiber detection electrode is analyzed. The group C = 0 and COOR content of carbon fiber electrode increase as the heat treatment temperature increases; the heat treatment reduces the capacitance effect of electrode, increases its exchange current density, and improve its linear performance and settling speed Keyword： ordnance science and technology; underwater electric field electrode; carbon fiber; heat treatment; self-noise; electrochemistry; X-ray photoelectron spectroscopy; Received： 2017-03—22 0引言 舰船电场是除了声场、水压场、磁场以外最重要的水下目标特性之一，已成为水 中兵器的重要追踪目标之一。由于舰船的金属构造、防腐蚀系统、推进系统、供 电系统等因素，舰船会产生明显的水下电场信号，利用这些电场信号可对舰船 进行检测、定位或者作为水中兵器的引信物理场。其中高性能水下电场传感器对 于水下电场检测至关重要〔1-2〕。 目前水下电场电极种类较多，主要有锌、Ag/Ag