Pd-CuFe3O4@C催化1,4-丁炔二醇选择性加氢的研究.DOCVIP

Pd-Cu/Fe304@C 催化 1, 4-丁炔二醇选择 性加氢的研究 任勇袁涛刘德蓉熊伟吴小海衣飞孟晓静 重庆科技学院化学化工学院 1, 4-丁烯二醇是一种高经济价值的精细化学品，1，4-丁炔二醇选择性加氢是制 备1，4-丁烯二醇的有效途径。本文采用浸渍法制备了双金属磁性催化剂 Pd-Cu/Fe30JC,利用X射线衍射(XRD)、乂射线光电子能谱(XPS)及透射电子 显微镜(TEM)等技术手段对催化剂进行了表征，考察了 Pd/Cu物质的量比、反 应温度、H2压力、反应吋间和催化剂用量等因素对催化剂性能的影响。结果表 明，在Pd/Cu物质的量之比1 : 1、催化剂/底物为1 : 90000、反应温度为50°C、 H2压力为4MPa、时间为25min的条件下，1，4-丁炔二醇选择性加氢的转化率和 选择性分别达到了 95. 2%和98. 3%。该催化剂不仅具有高催化活性和选择性，而 且易与反应产物实现磁性分离，为该过程的工业化应用奠定了基础。 关键词： Fe304@C载体;Pd-Cu双金属催化剂;1，4-丁炔二醇;1，4-丁烯二醇; 基金：重庆市人学生科技创新训练计划项目(201611551319)资助 Study on selective hydrogenation of 1, 4-butynediol by Pd-Cu/Fe304@C catalyst REN Yong YUAN Tao LIU De-rong XWNG Wei WU Xiao-hai YI Fei MENG Xiao-jing College o fChemistrvand ChemicalEng ineering, Chongqing University of Science and Technology; Abstract： 1，4-butene glycol is a kind of high commercial valuefine chemical. The effective way of preparing 1， 4-butylene glycol is the selective hydrogenation of 1, 4-butylene glycol. The double metal magnetic catalyst Pd-Cu/Fe30i@C was prepared by impregnation method and the catalyst was characterized by some technical approaches such as X ray diffraction (XRD) ， X ray photoelectron spectroscopy (XPS) , transmission electron microscopy (TEM) and so on. The influence catalyst performance effects of Pd/Cu molar ratio, reaction temperature, H2 pressure, reaction time and catalyst dosage were investigated. Under the optimized conditions (Pd/Cu=l : 1, substrate/catalyst=l/90 000, 50°C, 4 MPa, and 25 min) , the conversion and the selectivity of hydrogenation of 1, 4-butynediol could reached 95. 2%and 98. 3%, respectively. The catalyst not only had high catalytic activity and selectivity, but also easy to achieve magnetic separation with the reaction product, laying the foundation for the industrial application of the process. Keyword： Fe30補C support; Pd-Cu bimetallic catalyst; 1， 4-butynediol; 1， d-butenediol; 1，4-丁烯二醇(BED)是一种高经济价值的精细化学品，广泛应用于医药、化 工、造纸、烟草、电镀等行业。目前，Lindlar催化剂广泛用于1，4-丁炔二醇(BYD) 半加氢制备1，4-丁烯二醇，但在该催化工艺中，存在着掺杂的毒物铅会导致钯 催化剂