SBS的链结构与改性沥青性能的关联性.DOCVIP

SBS的链结构与改性沥青性能的关联性 李雪坤曹亚东罗勇 上海化工研宄院有限公司聚烯烃催化技术与高性能 材料国家重点实验室上海市聚烯烃催化技术重点实 验室上海公路桥梁（集团）有限公司 为寻找影响苯乙烯-丁二烯-苯乙烯嵌段共聚物（SBS）改性沥青性能的关键因素, 釆用FTIR、GPC和1HNMR对17种不同牌号市售SBS的主体结构、相对分子质量、 相对分子质量分布、聚丁二烯（PB）和聚苯乙烯（PS）嵌段物质的量比［n （PB） /n （PS）］、聚丁二烯段 1, 4-C=C 和 1, 2-C C 物质的量比［n （1, 4_） /n （1, 2-）］进行了表征与测试，结合SBS改性沥青三大性能［软化点（Ts）、延度 （Du）、针入度（NP）］的测试分析，探究了 SBS链结构对改性沥青三大性能的影 响。通过拟合SBS链结构参数与改性沥青三大性能实验数据，分别建立了改性沥 青软化点、延度和针入度与SBS的链结构参数之间的关联性方程。结果表明：改 性沥青的软化点与SBS相对分子质量（MJ呈曲线正相关，延度与Mn呈极值曲线 相关，针入度与MjDn （1，4_） /n （1，2-）呈曲线相关，本文建立的关联性方 程能够根据改性沥青性能预测所需专用SBS的链结构参数。 关键词： SBS;改性沥宵;链结构;关联性;建筑用化学品; Correlation between Chain Structures of SBS and Properties of Modified Asphalts LI Xue-kun CAO Ya-dong LUO Yong Shanghai Key Laboratory of Catalysis Technology for Polyolefins; Shanghai Road and Bridge (Group) Co.，Ltd.; Abstract： To investigate the key factors influencing the properties of styrenebutadienestyrene tri-block copolymer (SBS) modified asphalts the chain segment structure, molecular weight, molecular weight distribution, block ratio of polybutadiene (PB) to polystyrene (PS) [n (PB) /n (PS) ]mole ratio of 1, 4~C = C double bond and 1, 2-vinyl [n (1, 4~) /n (1, 2-) ] in PB of seventeen different commercial SBS samples were characterized by ETiR, GPC and lHNMR. The effects of chain structures [numberaverage molecular weight (Mn)，molecular weight distribution, n (PB) /n (PS) and n (1, 4~) /n (1, 2~) ]of SBS on the softening point (Ts) , ductility (Du) and needle penetration (NP) of modified asphalts were investigated. Tn addition, the correction equations between chain structure parameters of SBS and softening point, ductility and needle penetration of modified asphalts were established by fitting the experimental data, respectively. The results indicated that there was a positive curve correlation between softening point and Mnof SBS an extremum curve correlation between ductility and Mn， and negative curve correlations between needle penetration and both Mnand n (1，4-) /n (1，2-) ? According to the prop