工业级磷酸二氢钾除砷制备食品级聚偏磷酸钾.DOCVIP

工业级磷酸二氢钾除砷制备食品级聚偏 磷酸钾 錢厕丁一刚龙秉文 武汉工程大学化工与制药学院绿色化工过程教育部 重点实验室湖北样云（集团）化工股份有限公司 介绍了以工业级磷酸二氢钾为原料，通过去除微量的砷杂质制备食品级磷酸二 氢钾，再经过脱水聚合制备聚偏磷酸钾的方法。其中微量砷离子脱除是重要的一 步。除砷方法是将工业级磷酸二氢钾加热至熔融状态，利用氢卤酸与砷离子反应 生成低沸点的卤化砷，并在高温下气化分离出去，以达到脱除微量砷的目的， 得到食品级磷酸二氢钾。考察了反应时间、搅拌转速、卤化氢用量对除砷效果的 影响，当磷酸二氢钾与氢卤酸物质的量比低于16. 7、搅拌转速大于250 r/min、 反应时间在45 min以上时，可以使工业级磷酸二氢钾中的砷含量达到食品级磷 酸二氢钾的要求。采用化学分析以及X射线衍射（XRD）、红外光谱（TR）、拉 曼光谱（Raman）等表征手段，综合分析丫聚偏磷酸钟实验样品的黏度、分子组 成等，并与商业样品相比较，结果表明二者性质一致，并达到了国家标准的要 求。 关键词： 磷酸二氢钾;聚偏磷酸钾;卤化砷; 联系方式:bingwen_long@163. Production of food grade potassium polymetaphosphate from industrial potassium dihydrogen phosphate by trace arsenic removal Luo Wanzhi Yu Ying Ju Li Ding Yigang Long Bingwen Key Laboratory for Green Chemical Process of Ministry of Education， School of Chemical Engineering and Pharmacy， Wuhan Institute of Technology; Hubei Harvin (Group) Chemical Industry Company; Abstract： A preparation method for food grade potassium polymetaphosphate with industrial grade potassium dihydrogen phosphate as raw material, by removing trace arsenic to food grade potassium dihydrogen phosphate and by subsequent dehydration polymerization was introduced.It was of great importance that the trace arsenic removal in all the steps. During the removal, potassium dihydrogen phosphate was heated to a mol ten state at first, hydrogen halogen acid and arsenic ion had a reaction between each other so as to obtain low boiling point arsonium halide. Food grade potassium dihydrogen phosphate would be obtained after gasification separation at high temperature. The influences of reaction time, stirring speed and the amount of hydrogen halide on the removal effect were investigated. When the amount of substance ratio of potassium dihydrogen phosphate to halogen acid was lower than 16. 7, the stirring speed was higher than 250 r/min， and reaction time was above45 min, the arsenic content in industrial potassium dihydrogen phosphate could reache the standard of food grade. The structure and viscosity etc. of potassium