一种以异辛烷为燃料的新型固体氧化物燃料电池阳极研究-材料科学研究论文.pdfVIP

一种以异辛烷为燃料的新型固体氧化物燃料电池阳极研究 丁冬, 刘张波, 李磊, 冯凯, 夏长荣* ( 中国科学技术大学材料科学与工程系可再生洁净能源实验室，安徽合肥，230026) + Email: xiacr@ 关键词:碳氢化合物, 辛烷， 氧化铈包裹阳极，离子浸渍法，固体氧化物燃料电池 摘要 本文制备和研究了一种可用作直接异辛烷为燃料的固体氧化物燃料电池的阳极，该阳 极最大的特点是不需要贵金属钌作为催化剂。这种阳极由传统的电子导电材料镍作为骨架， 纳米尺寸的氧化钐掺杂氧化铈(SDC)作为氧离子导体通过离子浸渍法包裹在骨架上。跟传统 的镍陶瓷阳极相比，以异辛烷为燃料，该阳极作为支撑体的单电池显示出良好的运作稳定性， 电化学活性也得到进一步加强。在600 度其最大功率密度约为0.4 瓦特每平方厘米，并且在 260 小时的长期放电中维持保持性能的稳定。本文还进一步研究了燃料组分对电池稳定性的 影响，并对氧化剂重整进行了讨论。 Investigation of a novel anode for solid oxide fuel cells using iso-octane fuels Dong Ding, Zhangbo Liu, Lei Li, Kai Feng, Changrong Xia* Laboratory for Renewable Clean Energy, Department of Materials Science and Engineering, University of Science and Technology of China, Hefei, 230026 Anhui, China E-mail address: xiacr@, Tel: 86-551-3607475, Fax: 86-551-3607475 Abstract A Ru-free anode was developed for the direct utilization of iso-octane in solid oxide fuel cells (SOFCs). The anode was consisted of Ni frameworks and nano-sized oxygen-ion conductor, samaria-doped ceria (SDC), which was introduced via an ion impregnation process. Compared with the cells with conventional Ni-cermet anodes, the cells with SDC-coated Ni anodes showed improved stability and enhanced electrochemical activity. Peak power density of ~ 400 mW cm-2 was achieved at 600 oC, and power generation was relatively stable over 260 hours when iso-octane-air mixtures were directly used as the fuel. The fuel composition had great effect on cell stability, indicating the fuel cell performance could be further improved by adjusting iso-octane content in the mixtures. Keywords: Hydrocarbons; octane; ceria-coat