TiO2催化氧化工艺对饮用水中AOC的影响.docVIP

TiO2催化氧化工艺对饮用水中AOC的影响 第28卷第9期2007年9月环境科学 ENVIRONMENTALSCIENCE Vo1.28.No.9 See.,2007 03/TiO2催化氧化工艺对饮用水中AOC的影响 梁涛,马军,王胜军,杨忆新,张静 (哈尔滨工业大学市政环境[学院,哈尔滨150090) 摘要:以陶粒,硅胶和沸为载体,分别负载二氯化钛(TiO)进行臭氧催化氧化去除硝基苯的实验,并埘饮用水中生物可同化 有机碳(AOC)昕代表的小分子台机物(酮,醛,醇和羧酸类物质)的生成情况进行了研究.发现臭氧催化氧化比单纯的臭氧氧化 能更彻底地将部分大分子有机物氧化成小分子中间产物,陶粒,硅胶和沸百负载TiO:3种催化剂分别将AOC从大约300 1Lg?L增力【J到674.1lag?1..,847.2f』gL和882.1p-gL一,并且分别使AOC/FOC从原水的4.68%升高到3O.5%,33.21%和 46.04%,大大地提高丁水中仃饥物的可生物降解性.如果增加臭氧投量,催化氧化可使小分子有机物部分被氧化,致使水样 AOC又略有同降.存达一过中,AOCNOX所代表的羧酸类物硬急剧增加,达到总AOC的90%以j_=,取代AOCP17成为_r AOC的主体组成部分 关键词:AOC;催化氧化;0/TiO;小分子氧化副产物 中图分类号:X703I文献标识码:^文章编号:0250330I(2007ImpactsofAOCbyO3/TiO2CatalyticOxidationinDrinkingWater LIANGTao,MAJun,WANGSheng—jun,YANGYi—xin,zHANGling (SchoolofMunicipalandl~:nvirt)mnelltatEngineering,HarbinInstituteofTechnology,Harbin150090,China) Abstract:Thispaperpresentscatalyticoxidationwithtitaniumdioxidenano一[)articleshladedonseveralselectedcarriers,whichareceramic, silieagelandzeolite.1oreaalovenitrobenzenefromdrinkingwateriraozonation.Inthisstudyassimilableorganiccar})【)n(AOC)isourinterest andassumedasaparamelerresponsibleforlowmoleculeorganiccarbonsuchaskelone,aldehyde,alcoholsandcarboxylacidsindrinking water.Catalyticuxidaliolismoreeffectivethan0z(mati()naloneinthedegradationoflargerfractionsoforganicstolowerfractions,AOCwas increasedfrom300l~g/1to674.1la-gL.847.2p-gL～and8821lzgLbythecatalysisozonationofcerami/TiO:.silicagel/TiO2, cerami/TiO2respectively,aridtheproporlionofAOCinTOCcai~lbeincreasedfrom4.68%to30.5%,33.21%and46.04%.respectively. ThecatalyticoxidationPliIlancedthebiologradabilit)oforganicsinthewatergreatly.Withtheozonedosageincrease.AOCbegantoreduce slightlybecausetheh)wmolecularsizeorganiccart)OHwasmineralized.Intheprocesses,AOC—NOXconsistingofcarboxylacidmostly increasedrapidly.resultinginincreasei)ftheproportionofAOC—NOXinAOCover90%andlhemajorityofAOCturnedfroi71AOC—PI7to A0C—N0X. Keywords:AOC;catalyticozonation;0/TiO;lowmolecularsizefractionsoftheorganicmatter 高级氧化工艺是利用?OH氧化分解水中有机