8羟基喹啉为骨架的cu2ag配合物的合成结构及荧光性能研究 word格式.docxVIP

AbstractAs a new cutting-edge science，supramolecular chemistry is one current research臼. Molecul缸 recognition is a very impo此ant p缸t ofchet回stry，h掘a怕也tedmuchof many chemists in穹centyears. 8Hydroxyquinoline(8-HQ) unit is an idea1 bui1ding block ωconstruct supermolecul缸 struc阳re. wi也 its specific coordinate feature，it can bond metal ionsωself-assemble some oligomers possessing special capability. Th邸，扭曲扭曲创is，taking the 8-HQ as a body molecule，由自由w 8-HQ derivat臼部 ligand were s严也esized by modi命ing itsgroup，也m 也ec∞rdination behavior of the ligands and the structure of complexes w町estudied in detail to elucidate the v缸iety of those complex臼and the recogr咀tion ofsome叩ecial me阳1 ions while reg缸ding them 槌 a fluorescence probe，and some results list 槌following:Terpyridine(trpy) shows a good c∞rdination capability and its aromatic ring iseasi1y functionalized. 80，a new ligand，4-(4-[8-oxo叩linoline]benzyl)-2，2 :6，2-t臼pyridine，LI)is achieved by introducing 让 onto the backbone of 8-HQ，and five sup臼molecul町compound，[Hg(L1)Ch].2DMF(I) ， [Agz(L1)2(N03)2].2DMF(2) ， [A缸(L1)2(CI04)2].2DMF(匀， [CU2(U)z(N03)4].2DMF(4) ，[Cu2(L1)2(CI04)4].2DMF( 匀，W町e also prep缸ed. Based on the analysis of the crystal structur饵， the type of their hydrogen bonding，π·πstacking interaction and supramolecular struc阳re were full discussed. It indicates 也就， the asymme创c unit of complex (l) consists of twocrystallographic-separate complexesand twoDMFmolecul臼. Itextendsas atwo-dim臼lSional layered struc阳re 也rough the C-H...Cl H-bonds，C-H...O H-bonds and π·πstacking interaction between 也.e pyridine rings. The shape of complex (2) is a distorted box-like structure 岛rmed by [2+2]，也at is，two ligands and two sliv町 ions 缸e bonded in head-to-tr回1 pattem. Then through 由e existence of C-H...O H-bond，complex(2) stacks into a wave-like framework， and it also 岛und 也at the weak pyridine ring π·πstacking interactions occur between the neighboring mole心ules wi由 3.729 ? spatial distance; complex