ag2tebi2te3及其纳米复合热电材料的制备与性能研究 word格式.docxVIP

AbstractNowadays, with rapid development of economy and the increasingly shortage of energy, thermoelectric material which is a kind of clean and reproducible energy material is attracting widespread interest. The method of improve the thermoelectric properties makes the technology become the bottleneck of its being used in our daily life. Nano-composite technology could improve the thermoelectric properties of the thermoelectric material. In recent years, many scholars publish their new research results of high-powered nano composite thermoelectric material. In this paper, using hydrothermal(solvothermal) the one-dimensional Ag2Te nanowires and Bi2Te3 are prepared, and the precursors are tested on token and electrology characteristic. We had a research on the double hydrothermal and mechanical mixed methods synthesis of Ag2Te, Bi2Te3 and compounds with the first two precursors.The pure phase of precursors the Ag2Te is prepared; via the SEM, TEM et al, it isrevealed that the Ag2Te is the nano wire with the length of dozens of micron and the diameter of 200-300nm. After testing and analyzing its performance, the result reveals that the conductivity of Ag2Te is higher than the result that mentioned in the documents. Because of the phase variation, Seebeck coefficient’s singe changed, which indicates that Ag2Te changed from n-type semiconductor into p-type during the temperature-rise period.Having explored the manufacture craft of, we investigate the elements that might influence the appearance of pure phase Bi2Te3. The elements as viscosity and the surface tension of the menstruum alike all will influence the process of crystal nucleation and growth. With higher viscosity the crystal size is uniform , and will grow slower, which is can help the crystal growing into a structure which is more homogeneous. The coordination agent could adhere on some crystal face selectively, thus it influences the direction of the crystal’s growth and created different appearance of it.