一种新型含酰胺结构成核剂对聚丙烯结晶行为影响的研究-材料学专业论文.docx

浙江T业火学硕I：论文一种新型含酰胺结构成核剂对聚丙烯结晶行为影响的研究摘要成核剂是改善聚丙烯(PP)物理机械性能的常用助剂之一。本文 自主设计合成出一种含酰胺结构的成核剂Dl，采用傅里叶红外光谱 仪(FT．IR)、质谱(MS)、差示扫描量热仪(DSC)、带热台的偏光显 微镜(POM)分别表征了其结构、熔融、结晶性能。然后将成核剂Dl 与PP熔融混合，并用DSC、POM、扫描电子显微镜(SEM)等表征了 该混合物的非等温结晶性能、结晶形态等；采用广角X射线衍射(、似RD)表征了PP的结晶晶型，发现成核剂D1能诱导PP生成p晶。本文主要研究结论如下： l、设计合成了一种含酰胺结构的成核剂D1，DSC分析结果表明该成核剂为结晶性化合物，其熔点、清亮点和结晶温度分别为220．1℃、234．8℃，204．3℃。2、将成核剂D1与PP共混制备试样BDP，通过POM表征BDP 结晶过程发现：随温度降低，首先成核剂D1结晶生成针状晶体，然 后诱导PP在其表面形成横晶。3、通过SEM对BDP结晶后的刻蚀断面形貌发现：成核剂Dl 形成的针状晶体在PP基体中易发生聚集，导致PP附着在其表面结 晶后形成的横晶呈聚集状态。4、通过WXlm研究BDP结晶的晶型发现：成核剂Dl结晶后生成的针状晶体可以诱导PP生成D晶。浙江T业人学关键词：成核剂，a晶，p晶，横晶，PP浙江工业人学STUDY ON EFFECT OF AN DJ_NO、厂ATION ACYLAMINO NUCLEATn呵G AGENT ON THE CRYSTALLIZATIoN BEHAVl0R OF PoI■甲ROPYLENEAB STRACTThe nucleating agent is one of common additiVes to improVe the physical and mechanical propenies of PP．In this work，aIl innoVation nucleating agent D l with acylamino group was synthesized andcharact甜zedby Founer仃ansfom in劬red spectrometer(FT-IR)、Massspectm(MS)、 Difj睹rential scanning caloIIimet拶(DSC)and Polarization optical microscope with a hot—stage(POM)．The BDP composed of PP and D 1 was prc：pared in HA AKE Rotational Remoter．The nonisothermal c巧stallization behaViorc哕stal mo印hologyetched surface mo叩hologM and the c叮stal types were characterized by DSC，POM，Scanning Electron Microscope(S EM)，Wide angle X-ray di妇盹ction(WXRD)， respectiVely．The comparing of c眄stal types of BDP with PP revealed that the formation of p c叮stal c觚be induced by nucleating agent D 1． The research work of this study has been listed舔follows：(1)An innoVation nucleating agent D l with acylamino group was designed，synthesized and characterized by DSC．It was found that the melting point，clearing point and crystal point of the nucleating agent D l浙江工业人学was 220．9℃，234．8℃and 204．3℃，respectiVely．(2)The compound of nucleating agent D 1 and PPnamed as BDE was mixed in HAAKE Rotational Rheometer BDP was pr印ared by．The c巧stal behaVior of BDP was inVestigated by POM．、Ⅳhen the BDP was cooled，nucleating agent D 1