载银氧化锌二氧化钛复合粉体的制备及应用-环境工程专业论文.docx

中南人学硕士论文 摘要摘要目前无机抗菌剂中的银系和二氧化钛光催化抗菌剂己广泛应用于各 种产品中，但是银系抗菌剂中的银离子不太稳定且价格昂贵，影响其推广 应用；而二氧化钛虽同时具有抗菌和杀菌效应，且效果迅速，杀菌力强， 但受光照限制较大。因此本文设计开发了一种新型的载银复合抗菌剂，利 用氧化锌及二氧化钛为载体，然后载银制备载银复合抗菌材料。文章主要 研究了该新型抗菌剂的制备工艺条件，并考察了该载银复合粉体在陶瓷和 涂料中的应用效果。本研究采用共沉淀法制备“核一壳”型的载银载锌二氧化钛复合粉体， 使用DTA、XRD、SEM及紫外光谱等分析手段考察了经不同配比及热处 理条件下制备的复合粉体结构、形貌、粒度、白度及抗菌性、光催化性能 指标，研究结果表明：载入1 5wt％氧化锌、经500℃煅烧后得到的复合粉 体的白度较佳、分散较好、粒度较小。以该配比复合前驱体载银，载银量 为2％，经500℃热处理获得的载银复合粉体的光催化性能、抗菌性能、 色泽及稳定性较为理想。将合成的载银复合粉体添加至仿瓷釉料中及涂料中，制备抗菌陶瓷及抗菌涂料，并对其物化性能及抗菌性能进行研究，研究结果表明：在仿瓷 釉料中载入3wt％的复合抗菌粉体，经100℃干燥3h后得到具有良好的抗 菌持久性和基底附着强度且外观较好的仿瓷抗菌镀膜陶瓷。在涂料中载入 1．5wt％的抗菌剂，即获得具有良好的抗菌持久性和稳定性且装饰效果好 的抗菌涂料。关键词： 银；二氧化钛；锌；抗菌剂审南大学预圭论文 AbstractABSTRACTRecently,inorganic antibacterial materials such as silver-doped composite and photocatalytic agent of titania were used widely in many products，however silver is expensive and silver ion is unstable and easily transformed into black silver when exposed to the light．Although anti—bacteria function of Ti02 is effective，it is still confined by intensi够of ultraviolet．Therefore，we proposed to prepare a new kind of antibacterial material containing silver ion，zinc ion and titania in this work．The antibacterial composite powders with a coating film on the particle were prepared by simultaneity deposition methods。The structure and morphology of composite powders were investigated by DTA，XRD and SEM expecially．The properties of composite powders such as whiteness， antibacterial activity and photocatalytic activity were also characterized in thisstudy．Results show that the composite powder containing 1 5wt％ZnO， 2wt％Ag and annealed at 500℃has good whiteness and dispersion．The antibacterial ceramics and paint were prepared by the addition ofAg／Zre Ti02 composite powders．Both of their physical，chemistry andantibacterial performances were studied．The glaze film with 3wt％ Ag／Zn／Ti02 treated at 1 00℃for 3h and the paint with 1．5wt％Ag／Zn／Ti02 would exhibited good performance。Keyword：silver；titania；zinc；antibacterial agent．1，原创性声明本人声明，所呈交的学位论文是