基于高核多钒酸盐的金属-有机配合物的设计合成及其性能分析-无机化学专业论文.docx

基于高核多钒酸盐的金属-有机配合物的设计合成及其性能研究英文摘要TheSynthesis andPropertiesResearch ofMetal Organic CoordinationCompounds Basedon Polyoxovanadates withHighCoreAbstractThispaperpreparedaseriesofnewmetalorganiccoordinationcompoundsbythe reactionbetweentransitionmetal oralkaline-earthmetalsandpolyoxometallateor dicarboxylicacidligandsunderhydrothermalconditions.Atthesametime,thereacton conditons,thetopologytypesofthenetworkaswellasitsintermolecularforces,the ligandgeometryandotherlawswereanalyzedandsummarized.Ontheotherhand,we alsoexploredtherelationshipbetweenthestructuresofthenewmaterialsandtheir properties.WiththeexplorationofthereactionsolutionpH,temperaturesandingredients,we used situ synthesismethodandroomtemperatureaqueous solutionsynthesis technology successfullypreparingfivenewmetal-organicframeworkcomplexes;thesecompounds werecharacterizedbysinglecrystalX-raydiffraction,elementalanalysis,IRspectra andpowderX-raydiffraction.Furthermore,theelectrochemicalproperty,water solubilityandcatalyticactivityofthesesubstanceswerestudieddeeply.Underhydrothermalconditions,Byusingcoppernitrate,ammonium metavanadate and sodium dihydrogen phosphate as the additives and addingethylenediaminetoadjustthepH,twonewpolyoxovanadates clusterwereobtained：[Cu(en)2]4[Na2V16O42(VO4)]?2H2O(1)[Cu(en)2]5[V18O42(VO4)]?2H2O(en= ethylenediamine)(2)Compound1containsanovelbisodium-substituted[Na2V16O42(VO4)]cluster (Na2V16)withanencapsulated[VO4]core.TheNa2V16clusterexhibitsa eight-connectedmodelbyprovidingeightterminalOatomstolinkeight[Cu(en)2]units, generatingathree-dimensional(3D)network.Compound2isformedfromclassicalV18cluster encapsulating [VO4]. And constructed a three-dimensional network which英文摘要基于高核多钒酸盐的金属-有机配合物的设计合成及其性能研究similarwithCompound1via[Cu(en)2]linkingunits,Furthermore,theelectrochemical propertyof1hasbeen studied.ByusingNH4VO3,NaH2PO4andH2Oinhydrothermalreaction.Anew polyoxovanadatesclusterencapsulating [VO4]core:[Na(H2O)4][H4V18O42(VO4)]?16H2O(3)withgoodwater-solublepropertieswasobta