染料分子敏化半导体功能化石墨烯的制备及其光催化产氢的分析-物理化学专业论文.docxVIP

染料分子敏化半导体功能化石墨烯的制备及其光催化产氢的研究英文摘要The Preparation of Dye-sensitized Semiconductor/graphene Nanocomposites and its Application in Photocatalytic Hydrogen Evolution AbstractEnergy and environmental issues at a global level are important topics. It isindispensable to construct clean energy systems in order to solve the issues. Hydrogen as a clean, efficient, high calorific value and environmentally friendly fuel has received a wide publicity. One of the important ways to sustainable energy development is to utilizerenewable solar energy to realize photocatalytic hydrogen evolution.In this paper we use graphene as substrate material. A series of inorganic-organic nanocomposite functionalized graphene nanocomposites were prepared by a facile synthesized method. These nanocomposites were characterized and used as photocatalyst for water splitting. Some corresponding researches were done as follows:Ru(dcbpy)3/TiO2 was prepared by self-assembly method, Ru(dcbpy)3/TiO2/RGO composites were prepared by a modified one-step colloidal blending method. The structures of nanohybrid were characterized by XRD, Raman, FTIR and TEM. The results of UV-vis DRS and photocurrent enhancement of Ru(dcbpy)3/TiO2/RGO revealed that nanocomposites extend the light absorbance into visible regions and prolong the lifetime of photoinduced electron due to the present of RGO, which can accept and transfer electron effectively. Under the UV-vis light irradiation, the photocatalytic activity was enhanced effectively compared to those of TiO2, Ru(dcbpy)3/TiO2 or TiO2/RGO in EDTA solution. The catalytic activity of Ru(dcbpy)3/TiO2/RGO/Pt nanocomposite was influenced by the content of Ru(dcbpy)3 and pH value in system, and we also investigated the stability of catalyst. According to the experimental results, we explain the mechanism of hydrogen evolution over Ru(dcbpy)3/TiO2/RGO/Pt photocatalyst under visible light irradiation.TiO2/RGO/Pt nanocomposites were prepared by one-step solvot