dad和d单元桥联的多核环金属铱配合物的合成及其光电性能的分析word格式论文.docxVIP

AbstractsIn this context, the recent progresses in cyclometalated iridium complexes and organic light-emitting devices (OLEDs) have been described. In order to address the current problems for the iridium complex-based single-molecules white emission materials, such as relatively few types, poor color stability and low luminescent efficiency, two classes of multi-nuclear cyclometalated iridium complexes, which contains the linkage units of the donor-acceptor-donor (D-A-D) and donor-donor-donor (D-D1-D) structure between the phosphorescent chromophore,were designed and synthesized. Their molecular structures were characterized by 1HNMR, 13CNMR, elemental analysis and MALDI-TOF MS. The effect of bridged units and linkage mode on the thermal stability, photophysical and electroluminescent properties was studied. Single-dopant white organic light emitting diodes (WOLEDs) based on multi-nuclear cyclometalated iridium complexes were achieved.Main contents of this dissertation are summarized as follows:A class of dinuclear cyclometalated iridium complexes of (C8TPAFIrpic)2BT, (C8TPAFIrpic)2PZ and (C8TPAFIrpic)2AN linkaged via the conjugated D-A-D/D-D1-D bridged unit were obtained, in which D and D1 are triphenylamine (TPA) and anthracene (AN), respectively, as well as A are benzothiadiazole (BT) and phenazine (PZ) units. For comparision, another dinuclear cyclometalated iridium complex of (C8TPA- PhOC2FIrpic)2BT linkaged by non-conjugated D-A-D bridged unit was synthesized. All of these dinuclear cyclometalated iridium complexes exhibited good thermal stability with a decomposition temperature more than 340 °C at 5% weight loss. The D-A-D-based complexes of (C8TPAFIrpic)2BT, C8TPAFIrpic)2PZ and (C8TPAPhOC2FIrpic)2BT showed a stable red emission in the single-dopant and single-emissive-layer polymer light-emitting devices (PLEDs) at different concentrations and voltage. The maximum luminance of 6118 cd/m2 and the maximum current efficiency of 1.20 cd/A were obtained i