er0.4bi1.6o3sm0.2ce0.8o1.9双层电解质中温固体氧化物燃料电池的制备及性能分析word格式论文.docx

优秀毕业论文 精品参考文献资料 Abstract Solid oxide fuel cells (SOFCs) are the most efficient energy conversion devices, they produce electricity by an electrochemical reaction with negligible emissions. High operating temperature limit the commercialization of SOFCs. Higher ionic conductivity electrolytes are needed to improve the performance of SOFCs for a significant increase in ohmic polarization at low temperature. Alternative electrolyte materials, such as samaria doped ceria (SDC) and erbia stabilized bismuth (ESB) have 1-2 order of magnitude higher ionic conductivity than conventional yttria stabilized zirconia (YSZ) electrolyte. However, doped ceria becomes a mixed ionic-electronic conductor under a reducing atmosphere, while stabilized bismuth oxide decompose to metallic bismuth exposing a low oxygen partial pressure. In this work, Sm0.2Ce0.8O1.90 (SDC) powder was synthesized using a sol-gel combustion method. Er0.4Bi1.6O3 (ESB) powder was prepared by reverse chemical titration co-precipitation method. Symmetrical cells were constructed with Ag-ESB composite electrodes on both sides of SDC electrolytes. The impedance was measured using a Zahner Im6ex electrochemical workstation. A dry-pressing technique was used to prepare the pellets with NiO-SDC as the substrate anodes and SDC as the electrolytes, ESB thin films were deposited on the SDC electrolyte layer by spin coating method. The phase structure of as-prepared ESB powders and SDC powders was identified by X-ray diffraction analysis. Morphology and microstructure of the single cells with ESB/SDC bilayered electrolyte were observed using scanning electron microscopy. Anode supported single cells with various thickness of SDC electrolyte were tested to explore the effect of SDC thickness on the overall performance of the bilayer electrolyte cells, and compared to the single layer SDC electrolyte cells. XRD analysis shows both the as-prepared SDC powder and ESB powder exhibit cubic fluorite structure with no indication