基于超连续谱的时间分辨cars方法及技术分析-time - resolved cars method based on supercontinuum and its technical analysis.docx

anenoughbroadbandwidth,thespectralcontinuity,simultaneity,uniformityandstabilityof variousspectralcomponentsinsuperconyinuumareallnecessary.Thetheoreticalanalysisandnumericalsimulationarecarriedoutforobtainingtheexperimentalconditionstoimprovethesupercontinuum.ThemainopticalparametersofexistingPCF,suchasthedispersioncurve,zerodispersionwavelength,areobtainedbythefiniteelementmethod.ThedistributionsofthesupercontinuuminthefrequencyandtimedomainareexploredundervariousconditionswiththesplitstepFouriermethod.Andthetemporaldistributionsof variousspectralcomponentsinsupercontinuumareanalyzedwiththecross-correlationfrequency-resolvedopticalgatingmethod.Theexperimentalconditionsforimprovingsupercontinuumareobtainedwithnumericalsimulation.Itistheguidanceforachievingtherequiredsupercontinuumsource.(4)Basedonthetheoreticalanalysisandnumericalsimulation,anultra-broadbandT-CARSspectrometersystemissuccessfullyachieved.Themainparametersofsystemarecalibratedbymeasuringsomesampleswiththeknown Ramanspectrum, suchas thespectralresolution,simultaneouslydetectablespectralrange.Themolecularvibrationalspectrumsin387-4092cm-1ofavarietyoforganicsamplesareobtainedbyexperiments.Therelationshipsbetweenthe intensityofCARSsignalsandpumplaserarestudied.Thesimultaneousmeasurementofthedephasingtimeofvariousmolecularvibrationalmodesiscarriedout.Themaininnovationsare:Theexperimentalconditionsforimprovingsupercontinuumareobtainedwithnumericalsimulation.Thesupercontinuumlasersourceisachievedwiththegoodspectralcontinuity,simultaneity,uniformityandstability.Therequirementsonthesupercontinuumlasersourceoftheultra-broadbandT-CARSspectrographyaremet.Theultra-broadbandT-CARSspectrographybasedonthesupercontinuumisachieved.Theorganicmolecularvibrationalspectrumswithhighspectralresolutioncanbesimultaneouslyobtainedin387-4092cm-1.Ithasthecapabilitiesofquicklyandeffectivelydistinguishingdifferentcomponents.Therelaxationcoursesofvariousmolecularvibrationalmodesinthespectralcoveragecanbesimultaneouslymeasuredtoobta