金纳米材料的可控合成及微纳结构制备技术分析-controllable synthesis of gold nanomaterials and analysis of micro-nano structure preparation technology.docxVIP

mol/L 罗丹明 B 拉曼信号; 一维金纳米线和单壁碳纳米管组装的异质结结构其 IV 特性测试结果表明异质结结构单元具有明显的肖特基效应，电流开关比约为 106 。文中所研究 的异质结构将在纳米尺度电子器件和电化学传感中有潜在的应用价值。关键词：金纳米材料，电化学合成，维数形貌可控，表面拉曼增强，异质结Research on Controllable Synthesis of Multiple Morphologies of Gold Nanomaterials and Fabrication of Micro- and Nanostructure AbstractGold nanomaterials have attracted widespread interest both in scientific and technological communities due to their unique and excellent chemical and physical properties, such as catalytic activity, bio-compatible, novel electronic, optic and magnetic properties. The potential utility of such nanoscale materials includes catalysis, microelectronics, biological sensing, cell imaging, and cardiac patches as well as photothermal therapeutic. Gold nanomaterials are providing new development options for the exploitation of new semiconductor devices and further engineering application. The controllable synthesis of materials can represent the development of Micro nano technology in some extent. For harnessing the full potential of gold nanomaterials, a requisite goal in the development and preparation is the ability to controllably synthesize gold nanocrystal with well-defined and organized growth pattern. In the dissertation, in order to achieve an efficient strategy for selective and controllable fabrication gold nanomaterials with desirable dimensionality and morphology and better understanding the mechanism, electrodeposition and dielectrophoresis on the nano-material/electrode system, systematic variation of experimental parameters affecting aligning and orientation arrangement such as voltage, frequency and the patterns of the micromachined electrodes were investigated. Firstly, the gold nanocrystal was synthesized on the surface of the electrodes utilizing the integration of electrochemical deposition and dielectrophoresis with silicon micromachining techniques. On the basis of ?nite-element modelling of the electrode system in terms of the theory of dielectrophoresis and electromag