可见光催化材料纳米氧氮化钽制备及分解水制氢性能-preparation of visible photocatalytic material nano-oxygen tantalum nitride and its hydrogen production performance by decomposing water.docxVIP

96%，具有最好的光催化活性。为降低 TaON 的缺陷密度，在细颗粒 Ta2O5 粉体表面复合一层 ZrO2 纳米颗粒，氮化得到了 ZrO2/TaON 复合材料。界面处的钽离子 与 ZrO2 相互作用，有效抑制了低价钽离子的形成。为了进一步提高 ZrO2/TaON 复合光催剂的活性，于 ZrO2/TaON 的表面负载 RuO2 为助 催化剂，用 XRD、SEM 和 TEM 等表征，证明在 TaON 表面成功包 覆了 ZrO2 和 RuO2 颗粒，用光电流及光催化制氢反应器评价了复合材 料的光催化性能，在 RuO2 含量为 2wt%时活性最高，产氢速率为 5umol/h。以钽粉为原料，采用水热法制备了无定型的 Ta2O5，经氮化、氮 化后再氧化得到高活性的 γ-TaON，并与 CdS 复合形成异质结结构。 为抑制 CdS 在水溶液中的光腐蚀，在其表面包覆一层 ZnS。采用 X 射线衍射仪（XRD）、场发射扫描电子显微镜（FESEM）和透射电子 显微镜（TEM）对复合材料进行表征，表明 ZnS/CdS 颗粒成功的包 覆在 γ-TaON 光催化剂的表面。光电流结果表明其活性大幅提高。在 可见光照射下，ZnS/CdS/γ-TaON 复合光催化剂在甲酸溶液中表现出 最高的活性；当 ZnS/CdS 的含量为 20wt%时，产氢速率达到了 20umol/h。PREPARATION OF VISIBLE LIGHT PHOTOCATALYTIC NANOMETER TANTALUM OXYNITRIDE AND PROPERTIES OF SPLITTING WATER INTO HYDROGENABSTRACTPhotocatalytic water splitting using solar energy has received a great deal of attention since it has been considered as one of the potential ways to provide clean and renewable energy of H2. However, most of photocatalysts as found are only responsive under ultraviolet(UV) light, which accounts for only a small fraction (4%) of the solar spectmm on the earth surface. When N element is introduced into a transition metal oxide, the transition metal oxynitrides exhibit strong absorption in the visible region due to the higher valence band which consisted of hybridized N2p and O2p orbital. That can lead to potential photoeatalytic applications under visible-light excitation. In the past several years, there has been a growing concern about the synthesize of new types of high active visible-light-driven oxynitride photoeatalyst. In this paper, the TaON prepared by nitriding reaction and a transition metal oxide as a material for the nitridation reaction, TaON with a narrow energy gap and visible light responsive photocatalysts.The Ta2O5 prepared by rapid hydrolysis reaction, the optimum reaction conditions: the temperature is 850℃, ammonia flowing rate of 90ml/min, nitriding time is 10h . And the samples characterized by X-raydiffraction, UV-VIS, and field emission scannin