锂离子电池正极材料limnpo4的制备及改性分析-preparation and modification analysis of limn po4 cathode material for lithium ion batteries.docxVIP

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锂离子电池正极材料limnpo4的制备及改性分析-preparation and modification analysis of limn po4 cathode material for lithium ion batteries.docx

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锂离子电池正极材料limnpo4的制备及改性分析-preparation and modification analysis of limn po4 cathode material for lithium ion batteries

AbstractThedevelopmentofcathodematerialswiththemeritsofhighenergydensity,safety,lowcosthasalwaysbeenthedrivenforceforthelarge-scaleapplicationsoflithium-ionbatteries.Olivine-typeLiMnPO4materialowningtheadvantagessuchashighpotential(4.1V,vs.Li+/Li),largetheoreticalenergydensity(697Whkg-1),excellentelectrochemicalandthermalstability,richmanganeseresources,lowcostandwithoutpollution,isexpectedtoplayanactiveroleinthefieldofpowerbatteries,andthushascausedtheresearchupsurgeincreasingly.ThechallengesLiMnPO4materialfacingarethepoorelectronicconductivityduetoitsinsulativity,andtheextremelowionicconductivityasaresultoftheinherentcharacteristicsoftheolivinestructurewhichlimitstheLi+onlydiffusingintheone-dimensionalchannel.Inordertoovercometheaboveproblems,wehavecarriedouttheresearchesonLiMnPO4bysurfacecarboncoating,bulkphasesingleiondoping,andthesynthesisofternarymaterials.Originally,thecarbon-coatedLiMnPO4/Ccompositeswereobtainedthroughsolid-statereaction,andtheinfluencesofvariouscarbonsources,carboncontents,calcinationtemperatureandtimeonthemorphologies,crystallinestructuresandelectrochemicalperformanceswerediscussed,respectively.Theresultsrevealthatthesamplescalcinedat750?Cfor8husingsucroseascarbonsource(15wt%carbon)showthebestelectrochemicalperformancesduetothefinestparticlesizeandtheoptimalreversibilityofelectrodesunderthiscondition.Thedischargecapacitiesare109.8,106.2and90.3mAhg-1at0.02C,0.05Cand0.2C,respectively.Moreover,thecyclingstabilitiesarethemostoutstandingunderas-statedcurrentdensities.Onthebasisofaboveoptimizedcondition,aseriesofsolidsolutionmaterialsLiMn1-xFexPO4withdifferentFe2+contents(x=0,0.2,0.3,0.5)weresynthesized.ThedopingofFe2+hasreducedtheelectrochemicalpolarization,resultingintheimprovementinthefollowingaspectssuchasthereversibilityofelectrodes,theabilityofdelithiation/lithiation,andtheionicconductivity.TheLiMn0.7Fe0.3PO4/Ccompositeshavethelowestchargetransferimpedance,andthediffusioncoefficientofLi+hasincreasedtwoordersofmagnitudes(from10-14cm2s-1inpr