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la23ca13mno3铁氧体复合体系的研制-preparation of la 23c a13 mno 3 ferrite composite system
和反铁磁性铁电体BiFeO3作为第二相进行复合,探讨不同磁性材料引入对复合系统电磁性质的影响。4、通过异质掺杂对基体铁磁金属颗粒界面的改性行为,研究不同含量反铁磁绝缘体MnCr2O4对(1-x)La2/3(Ca2/3Sr1/3)1/3MnO3/xMnCr2O4复合体系电、磁输运行为的影响。实验结果显示,在电输运行为上得到了明显不同于纯La2/3(Ca2/3Sr1/3)1/3MnO3的现象,在较低温度有一个新的金属-绝缘体相变过程;高场及低场磁电阻有明显提高。关键词:钙钛矿锰氧化物,低场磁电阻,颗粒复合系统,自旋极化隧穿AbstractRecentlygrowingattentionhasbeenpaidonthegrainboundaryeffectinpolycrystallineperovskitemanganitesofthetypeLn1-xTxMnO3(Lnisrareearth,Tisdivalentcation).Lastyears,colossalmagnetoresistance(CMR)effectwasobservedinthiskindofmaterials.However,theintrinsicCMReffectintheperovskitemanganitesisonlytriggeredathighmagneticfieldsofseveraltesla,whichrestrainsitsuseforpracticalapplications.Recentlygrowingattentionisbeingpaidtopolycrystallinemanganitesinwhichthegrainboundaryeffectsdramaticallymodifytheirphysicalproperties.Anattractivefeatureforthepolycrystallinemanganitesisalargemagnetoresistance(MR)atverylowmagneticfieldoverwidetemperaturerangebelowTp.Thelowfieldmagnetoresistanceinpolycrystallinemanganitesisusuallythoughttobearesultofthespinpolarizedtunnellingthroughenergybarriersatthegrainboundaries.Thestructuraldisorderedinterfacesplayaroleoftheenergybarrierforcarriers.ThemagnetoresistancecanbeenhancedthroughcontrollingthegrainboundaryeffectbyformingcompositesoftheCMRoxideswithsecondaryphases.However,inthesecompositesystems,theenhancedLFMRwasusuallyobservedatlowertemperature,whichrestrainsitsuseforpracticalapplications.Inthispaper,CMRgranularcompositesystemswereinvestigated.Usingdifferentmotheds,WediscussedtheeffectsofthesecondphaseonthestructureandtransportpropertiesoftheCMRcomposites.Themaininvestigationincluding:Anintroductionofspintronicshasbeenpresented.Moreattentionshavebeenpaidonthestructure,electricaltransportbehavior,andmagneticpropertiesofperovskitemanganites.OnthebasisofthereviewoftheintrinsicCMReffectandextrinsiclow-fieldmagnatoresistance(LFMR)inperovskitemanganites,thebasicthinkingofsubjectselectionandinvestigationsignificanceisputforward.Thispartaimsatthepreparationmethodsandrelatedtesttechnologyofth
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