铋基纳米结构的可控合成及其光催化性能分析-controllable synthesis and photocatalytic performance analysis of bismuth-based nanostructures.docx

样品进行热处理时，发现热处理温度为 400oC 时，量子点开始消失，且会引起样品 光催化性能的明显降低。本文还依据所进行的 Bi-W-Cl-O 溶剂热体系的反应动力学 分析结果，尝试合成了 Bi2WO6/BiOCl 复合光催化材料，测试发现这种具有异质结 性质的样品具有更好的光催化活性。关键词：铋基纳米结构 BiOCl Bi2WO6 可控合成 Oriented-Attachment 机制 光 催化性能AbstractWith the improvement of living standard, more and more attention has been paid to environmental pollution issue. Photocatalysis is a newly developed technology which utilizes semiconductor materials to degrade organic dyes in water and poisonous gases in air. The photocatalytic process is energetically driven by UV or visible light and the final products are CO2 and H2O, which endows the technology with green and environment-friendly characteristics. And thus a great application potential in the treatment of pollution is expected. Bismuth-based nanostructures are a class of new high performance photocatalysts and in this thesis, we systematically investigated the controlled synthesis and photocatalytic activity of this kind of materials, typically indcluding BiOCl and Bi2WO6.The mesoporous BiOCl nanostructures were synthesized by a facile non-template lowtemperature solvothermal method using ethylene glycol as solvent . The urea was used to affect the crystal growth process and thus realize the controllable synthesis. With the increase of the addition amount of urea into the recipe, the microstructure of the samples changed from non-porous to mesoporous and the mesoporous BiOCl sample exhibited much higher photocatalytic activity. The synthesized sample was then modified with Pt nanoparticles through impregnation method. The photocatalytic activity of Pt/BiOCl sample increased obviously and the photodegradation process of toluene was changed, leading to the inhibition of the formation of more poisonous formaldehyde. Furthermore, we also annealed the as-prepared sample to control the oxygen defects and thus investigated the effect of oxygen vacancy defects on the photocatalytic activity of BiOCl samples. It was found the photocatalytic efficiency could be stren