不同方式引入亚微米mc型增强相激光合金化行为-laser alloying behavior of submicrometer mc - type reinforcing phase introduced in different ways.docxVIP

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不同方式引入亚微米mc型增强相激光合金化行为-laser alloying behavior of submicrometer mc - type reinforcing phase introduced in different ways.docx

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不同方式引入亚微米mc型增强相激光合金化行为-laser alloying behavior of submicrometer mc - type reinforcing phase introduced in different ways

磨性最好；T10钢中C含量较高，残余奥氏体加工硬化将转变为针状马氏体，45钢中C含量相对降低，合金化层中马氏体为板条状和针状，针状马氏体比板条状马氏体的亚结构中孪晶数量多，强化效果更显著。关键词：激光合金化；原位合成；直接添加；亚微米MC；显微组织；耐磨AbstractMedium-carbonsteel,high-carbonsteelandcastiron,whichhavelowpriceandgoodperformance,arewidelyusedinmanufacturingoftransmissionparts,shafts,fastenersandmoulds.Thesepartsrequireahigherwearresistanceofthesurfaceinworking.Inordertodevelopakindofalloypowdercompositedofbasepowderandreinforcementphase,whichcanbeappliedonthesubstrateofmedium-carbonsteel,high-carbonsteelandcastiron,TiCreinforcedFe-basedcompositecoatingswerepreparedon45steel,T10steelandCrMocastironbylaseralloying.Therewerethreeintroductionwaysofthereinforcement,namelyinsitureactionofTiandC,insitureactionofTiO2andCandnativeC5Ti4Wdirectaddition.SEM,EDAX,XRD,microhardnesstesterandtheweartestmachinewereappliedtotestthemicrostructureandpropertiesofalloylayers.Strengtheningmechanismwasstudied.Inoptimizationofthebasepowdercomposition,itwasfoundthatthecompatibilitybetweenbasepowderandsubstrateswasreflectedintheCcontent.Toeliminatecracksincoatings,thehigherCcontentinthesubstrate,thelowerCcontentshouldbeinthebasepowder.ButCrMocastironhadabadformabilityandcracksinitssurfacecan’tberemovedbyreducingCcontent.Whenreinforcementcontentreaches35%,thebeststrengthenedalloylayercanbeprepared.InsitureactionofTiandCon45steelobtainedthebestwearresistance.Samephasesconstitutedthealloylayers,namelyresidualaustenite,martensite,andMCtypecarbide.Compatibilitybetweencarbideaddeddirectlyintothecoatingandmatrixwaspoor,soitwaseasyforcarbidetowearoffthematrixandtheworstwearresistancewasgot.MC-typedcarbidesintroducedbyinsitureactionhadagoodcompatibilitywiththematrixandcubicgranularonesweredispersedinthematrix.ReactionbetweenTiO2andCcausedtheconsumptionofsolid-solutionCinFe-base.ItledtorightshiftoftheCcurve,improvementoftheaustenitestabilityandlowermartensitecontent.SobothhardnessandwearresistancewerelowerthanthereactionbetweenTiandC.InsitureactionofTiandConT10steelobtainedthebestwearresistance.Samephasesconstitu