self-combustion synthesis of na3v2(po4)3 nanoparticles coated with carbon shell as cathode materials for sodium-ion batteries：对na3v2自燃烧合成（po4）碳壳作为钠离子电池正极材料纳米涂层3.pdfVIP

Electrochimica Acta 155 (2015) 23–28 Contents lists available at ScienceDirect Electrochimica Acta journa l home page : www.e /loca te/ele cta cta Self-combustion synthesis of Na V (PO ) nanoparticles coated with 3 2 4 3 carbon shell as cathode materials for sodium-ion batteries Hui Wang, Danlu Jiang, Yan Zhang, Guopeng Li, Xinzheng Lan, Honghai Zhong, Zhongping Zhang, Yang Jiang * School of Materials Science and Engineering, Hefei University of Technology, Hefei, Anhui 230009, PR China A R T I C L E I N F O A B S T R A C T Article history: The real applications of Na V (PO ) cathode material for sodium batteries have been hindered by low- 3 2 4 3 Received 9 November 2014 cost and facile synthesis method. Herein, we report a facile self-combustion method to synthesize Received in revised form 18 December 2014 Na V (PO ) nanoparticles coated with carbon shell (NVP/C). Using as the cathode, the NVP/C is capable 3 2 4 3 Accepted 30 December 2014 of delivering the initial discharge and charge capacities of 100.72 and 111.3 mAh g1 at the current of 0.1 C Available online 7 January 2015 in a voltage of 2.5–3.8 V, and the capacity retention of the sample is approximately 95% of its initial specific capacity after 50th cycl