分隔二吡唑类配体的d10金属ⅰ,ⅱ配位聚合物的孔性 固相转化和发光性质-pore solid phase transformation and luminescent properties of d10 metal ⅰ, ⅱ coordination polymers separating pyrazole ligands.docx

学位论文原创性声明本论文是我个人在导师指导下进行的工作研究及取得的研究成果。论文中除了特别加以标注和致谢的地方外，不包含其他人或其它机构已经发表或撰写过的研究成果。对本文的研究做出贡献的个人和集体，均已在论文中以明确方式标明。本人完全意识到本声明的法律责任由本人承担。作者签名：日期：年月日学位论文使用授权声明本人授权汕头大学保存本学位论文的电子和纸质文档，允许论文被查阅和借阅；学校可将本学位论文的全部或部分内容编入有关数据库进行检索，可以采用影印、缩印或其它复制手段保存和汇编论文；学校可以向国家有关部门或机构送交论文并授权其保存、借阅或上网公布本学位论文的全部或部分内容。对于保密的论文，按照保密的有关规定和程序处理。本论文属于：保密（），在年解密后适用本授权声明。不保密（）。（请在以上括号内打“√”）作者签名：导师签名：日期：年月日日期：年月日目录摘要··········································································································IAbstract······································································································III第一章前言11.1配位聚合物化学研究进展·······································································11.2配合物的合成及影响配合物结构的因素·····················································21.2.1溶剂(水)热法··············································································21.2.2影响配合物结构的因素·································································31.3配位聚合物的光学性能··········································································61.3.1配合物发光的机理·······································································61.3.2d10金属配合物的发光优势81.4多孔配位聚合物···················································································81.4.1多孔配合物的同质异构和异质同构··················································91.5吡唑的配位化学·················································································101.6本论文的选题意义及目的·····································································12参考文献····································································································15第二章配体的合成、结构及发光性质·······························································192.1引言·······························································································192.2实验试剂和仪器·················································································202.3配体的合成······················································································202.4配体的分子结构及性质测定·································