pd改性的钙钛矿型或水滑石基高性能碳烟燃烧催化剂分析-analysis of pd modified perovskite or hydrotalcite-based high performance soot combustion catalyst.docx

oxidation activity, meanwhile, the presence of K helps to release Pd species to participate in soot combustion. The functions of K are summarized in the following aspects: (1) to promote the release of Co and Pd species and increase the active sites;(2) to improve the mobility of surface lattice oxygen; (3) to facilitate the adsorption of NO on the surface of the catalysts. The roles of Pd could be attributed to two points: (1) to modify the redoxidibility of the catalysts; (2) to increase the catalytic oxidation of NO to NO2. It is revealed by in situ FT-IR that there are three reaction pathways for soot combustion: namely direct soot oxidation by surface adsorbed oxygen species, the NO2-assisted soot oxidation and nitrate-assisted soot oxidation.Finally, Mg was added to K/Pd promoted CoAl-based hydrotalcite-derivedcomplex oxides to improve their activity for soot combustion. The study found the functions of K and Pd are similar with the CoAl-based hydrotalcite-derived complex oxide catalysts, while the effects of Mg are entirely opposite in different catalysts. On the one hand, it can generate strong interaction with the doped Pd in Pd substituted catalysts to inhibit the promotion of K; on the other hand, it can provide basic sites to K/Pd simultaneously supported catalyst to accelerate soot combustion. The results of in situ FT-IR are also similar to CoAl-based hydrotalcite-derived complex oxide catalysts. In addition, the thermal stability of CoAl-based and Co2.5Mg0.5Al-based catalysts are compared with the conventional supported catalyst Pd/Al2O3, which indicates that Pd in K/Pd supported hydrotalcite-derived complex oxide catalysts could prevent the sintering of Pd due to the strong interaction between Pd and other ions in the hydrotalcite-derived complex oxides.KEY WORDS：Soot combustion, Nitrogen oxides, Noble metal, Perovskite, Hydrotalcite-based mixed oxides, Reaction pathway目录第一章 绪论..................................................................