新型芳香族蓝色荧光材料的合成及性能分析-synthesis and properties analysis of novel aromatic blue fluorescent materials.docxVIP

AbstractOrganic light emitting diode (OLED) has been throught a great breakthrough in the past twenty years. In the three primary colors, red and green materials have reached the practical requirements. However, the low efficiency, short lifetime of the blue device is still the bottleneck of full-color display. Therefore, how to prepare high efficient and long lifetime blue OLED is still a great challenge. In this dissertation, a series of new blue materials are designed and synthesized. The related points of the work are summarized as followed:Carbazole possesses rigid plane structure, large conjugate system and good inter molecular holetransporting ability. Here, we designed and synthesized a series of new anthracene derivatives by 1,4-dimethylbenzene conjugated anthracene and carbazole: 3-(2,5-dimethyl-4-(10-(naphthalen-1-yl)anthracen-9-yl)phenyl)-9-phenylcarbazole(1-PCPAN), 3-(2,5-dimethyl-4-(10-(naphthalen-2-yl)anthracen-9-yl)phenyl)-9-phenylcarbazole(1-PCPAN), 3-(4-(anthracen-9-yl)-2,5-dimethylphenyl)-9-phenylcarbazole(PCPA),3,6-bis(4-(anthracen-9-y l)-2,5-dimethylphenyl)-9-phenyl-9H-carbazole(PDADPC). These materials have good thermalstability, and exhibit high glass transition temperatures over 140 ℃and decompositiontemperatures over 410 ℃. The device structure of the non-doped blue OLED is as followed：ITO/2-TNATA(60 nm)/NPB(10 nm)/Host(30 nm)/Alq3(25 nm)/LiF(1 nm)/Al (150 nm). It exhibits a maxinum current efficiency of 5.6 cd/A, a maxinum external quantum efficiency of 3.3% `with CIE chromaticity coordinates (0.15, 0.20) When 1-PCPAN was used as emitter.We used the tetraphenylethylene as central cores conjugated with electron-transporting imidazole derivatives designed and synthesized two new blue guest materials, (E)-1,2-diphenyl-1,2-bis(4-(1,4,5-triphenyl-1H-imid-azol-2-yl)phenyl)ethane(DPTPIE) and (E)-1,2-diphenyl-1,2-bis(4-(1-phenyl-1H-phenanthro[9,10-d]imidazol-2-yl)phenyl)ethane(DPP PIE). DPTPIE and DPPPIE exhibit good thermal stability and