新型稀土多硅酸盐发光材料的凝胶-燃烧法制备及性能分析-preparation and performance analysis of new rare earth polysilicate luminescent materials by gel-combustion method.docxVIP

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新型稀土多硅酸盐发光材料的凝胶-燃烧法制备及性能分析-preparation and performance analysis of new rare earth polysilicate luminescent materials by gel-combustion method.docx

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新型稀土多硅酸盐发光材料的凝胶-燃烧法制备及性能分析-preparation and performance analysis of new rare earth polysilicate luminescent materials by gel-combustion method

AbstractThenovelblueemittingphosphorSr3MgSi3O10:Eu2+withbroadexcitationbandwassynthesizedbythegel-combustionethodinaweakreductiveenvironment.TheresultsshowthatSr3MgSi3O10:Eu2+phosphorspossessthetetragonalcrystalstructuresimilartothatofSr2MgSi2O7.TheexcitationspectrumofSr3MgSi3O10:Eu2+isabroadbandintherangeof250–450nm,andthemainpeakisat366nmandthesecondarypeakisat394nm.Therefore,thisphosphorcanbeexcitedefficientlybyInGaNchipintherangeof350–410nm.Theemissionspectrumexcitedby366nmshowsawidebandwiththemainpeakatabout466nm,whichisascribedtothetypicaltransitionfrom4f5dto4fofEu2+.ItisfoundthattheluminescentintensityofSr3MgSi3O10:Eu2+phosphorsincreaseswiththeincreaseofreductivetemperature.Moreover,theluminescentintensityincreaseswiththeincreaseofEu2+content(inmole,thesamebelow),andreachesthemaximumwhenthecontentofEu2+is10%,andthendecreaseswiththefurtherincreaseofEu2+content,namelytheconcentrationquenchingoccurs.Theconcentrationquenchingiscausedbytheinteractionofelectricdipole-electricquadrupoleofEu2+accordingtotheDextertheory.High-brightnessblueemittingphosphorsSr3MgSi3O10:Eu2+,Er3+weresynthesizedsuccessfullybygel-combustionmethodinweakreductiveenvironment.TheresultsshowthatSr3MgSi3O10:Eu2+,Er3+phosphorspossessthetetragonalcrystalstructuresimilartothatofSr2MgSi2O7.Theexcitationspectrumshowsabroadbandfrom250nmto450nm,andthestrongestexcitationpeakisat357nm.Theemissionspectrumexcitedby357nmalsoshowsawidebandwiththemainpeakatabout466nm,whichisascribedtothetypicaltransitionfrom4f65d1to4f7ofEu2+.Accordingtotheemissionspectrumofas-synthesizedSr3MgSi3O10:Eu2+,Er3+andempiricalformulaofVanUitert,itcanbededucedthatEu2+ionsoccupySr2+siteswithcoordinationnumber8inSr3MgSi3O10host.Itisfoundthatco-dopedEr3+cansensitizeeffectivelytheluninescenceofEu2+ionsinSr3MgSi3O10host.Theluminescenceintensityreachesthestrongestwhenthemolefractionofco-dopedEr3+is0.04,anditisabout3.3timesofsingle-dopedEu2+sample.Anewred-emittingphosphorLa2Si2O7:Eu3+wassynthesizedbygel-combustionmethod.Theresultsshowthatth