一维纳米杂化材料的光电传感性质及在环境检测中的分析-photoelectric sensing properties of one-dimensional nano hybrid materials and their analysis in environmental detection.docx

SWCNT-HFIPP and SWCNT-HFIPPH have been obtained. Considered that strong hydrogen-bonding can be formed between hexafluoroisopropanol groups and dimethyl methylphosphonate (DMMP) (simulant of nerve agent sarin), two hybridized material sensing devices have been fabricated and utilized to detect DMMP. Excellent sensitivity and selectivity of the hybridized devices suggest that they have great capability of detecting explosives and chemical warfare agents.(2) Novel SWCNT-PCD hybrids have been successfully synthesized through in situ diazonium reaction between mono-6-deoxy-6-(p-aminophenylamino)-β-cyclodextrin (PCD) and SWCNTs for the first time. The cyclodextrin (CD) groups bind to the SWCNT surfaces through covalent interactions. Based on the sensing materials, fabricated chemical sensors of SWCNT-PCD hybrids have been utilized to detect Persistent Organic Pollutants (POPs), which exhibit excellent sensitivity and selectivity due to the concept of molecular recognition. The equilibrium constant values for the complexation of the PCD with the different POPs correlate with the magnitudes of the conductance change ratios of the SWCNT-PCD devices after binding of these POPs molecules, which can be suggested as potential applications in environmental monitor.（3）The as-prepared GNRs with different aspect ratios have been decorated withmono-6-thio-β-cyclodextrin so as to efficiently capture and detect methyl parathion insecticide via surface enhanced Raman scattering (SERS) technique for the first time. Detailed comparison among different aspect ratios of the GNRs suggests that the GNRs with aspect ratio 2 can be provided as excellent SERS active substrate for detecting the insecticide in the present study. Due to efficient formation of host-guest between hybridized cavity and methyl parathion, identification of the insecticide can be observed at picomolar level according to the fingerprint Raman peaks. Excellent sensitivity and selectivity for detection of the insecticide