路易斯酸法消融金属酞菁的技术及应用研究.pdfVIP

上海交通大学硕士论文 路易斯酸法溶解金属酞菁的技术及应用研究 摘 要 本文利用溶剂法成功制备了α、β、γ、ε、δ五种不同晶型的铜酞菁， 并利用溶剂转相机理对α和β晶型之间的转变进行了解释。用路易斯酸 配位法溶解了铜酞菁，并对其溶解机理进行了简单探讨。研究结果表明， 由于铜酞菁与路易斯酸形成了配合物，而这种配合物在极性非质子溶剂 中有良好的溶解性，从而导致了铜酞菁在路易斯酸和非质子溶剂中的溶 解。 用路易斯酸溶解配位法和微射流纳米分散技术相结合的方法成功 制备了铜酞菁纳米粒子。经微射流纳米分散仪6 次循环后，当所用分散 剂为OP-10 时，铜酞菁最小粒径可以达到221nm ；当所用分散剂为OP-10 和PVP 时，铜酞菁最小粒径可以达到180nm。 用邻苯二甲酸酐路线制备了六种金属酞菁，并用路易斯酸溶解配位 法溶解了这六种金属酞菁，用浸渍法使得这些金属酞菁负载于活性炭 上，得到了负载有金属酞菁的活性炭。NiPc/C ， Al(OH)Pc/C ， ZnPc/C ， PtPc/C ， FePc/C ， CoPc/C 。最后用光电子能谱，氮气吸附仪，热重分 析仪对这些负载有金属酞菁的活性炭(MPc/C)进行了表征，结果表明： 活性炭所负载的金属元素的含量为1%-2%(wt.)。在这些金属元素中，除 铝和铁的化合价为+3 价外，其余金属元素的化合价均为+2 价。热重分 析数据表明，活性炭负载锌酞菁的热稳定性最好，活性炭负载钴酞菁的 热稳定性最差。 关键词：晶型，纳米粒子，路易斯酸配位法，活性炭，金属酞菁，浸渍 法，负载 上海交通大学硕士论文 STUDY ON TECHNOLOGY AND APPLICATION OF LEWIS ACID DISSOLVING METAL PHTHALOCYANIN ABSTRACT In this paper, five different polymorphisms of copper phthalocyanine (CuPc) -α、β、γ、ε、δ were prepared by treatment with different solvents. And the process of α→β transformation was explained by classic phase transition with solvent. CuPc was dissolved by the method of Lewis acid complexation-mediated solubilization (LAPS), whose mechanism was discussed. The results of research showed that CuPc can form complex with Lewis acid which is soluble in aprotic solvent, leading to CuPc can dissolve in Lewis acid and aprotic solvent. The nanoparticles of CuPc were prepared by LAPS and microfluidize technique. After CuPc was treated by six passes of microfluidizer during the post-processing, the diameter can be diminished by 221nm when the OP-10 was used as dispersant, and the diameter can be diminished by 180nm when the OP-10 and PVP were used as dispersants commonly. Six kinds of metal phthalocyanine (MPc) were prepared by phthalic an