阈值光电子 光离子符合成像研究no c 3 πv=0态解离动力学-study on dissociation kinetics of no c 3 π v = 0 state by threshold photoelectron photoelectron photo - ion coincidence imaging.docxVIP

摘要笔者参与建造了一套阈值光电子-光离子符合成像（TPEPICO-imaging）装 置，并用这套装置研究了 NO 分子电离为 c 3Π(v’=0)态 NO+的解离电离（DPI） 动力学过程。在使用垂直分子束的情况下，通过一些近似并用矢量加法规则推 导了碎片离子在质心坐标系和最可几质心坐标系中的速度，飞行时间和在速度 图像中的位移之间关系。应用这些关系，得到并讨论了 N+碎片离子在质心坐标 系中速度及在最可几质心坐标系中的速度和角度分布。本文共分三章。第一章绪论，简介一些与离子成像和光电离、光解离等有 关的一些知识；第二章实验装置，介绍了同步辐射的一些知识，以及原子与分子物理（U14-A）光束线及新研制的 TPEPICO-imaging 装置；第三章阈值光电 子-光离子符合成像研究 NO+ c3Π(v’=0)态解离动力学，推导了碎片离子在质心 坐标系和最可几质心坐标系中的速度，飞行时间和在速度图像中的位移之间的关系，并用这些关系得到并讨论了 N+碎片离子在质心坐标系中速度及在最可几 质心坐标系中的速度和角度分布。关键词：阈值光电子-光离子符合成像，速度成像，质心，最可几质心，一氧化氮，动能，释放动能，角度分布，各项异性参数，同步辐射 ABSTRACTThe author participated the development of the new apparatus of threshold photoelectron-photoion coincidence imaging(TPEPICO-imaging), and the dissociation dynamics of NO+ at c 3Π(v’=0)state produced through the ionization of NO molecules was studied using this apparatus. The relations between velocity in center of mass (CM) coordinates and most probable center of mass (MPCM) coordinates, time of flight (TOF) and displacement in the velocity map image of fragment ions are derived using vector addition of velocity and displacement on the condition of perpendicular molecular beam (MB). Using these relations the velocity in CM coordinates, the velocity and angular distribution of N+ fragment ions in MPCM coordinates are obtained and discussed, respectively.There are three chapters. In chapter one, which is introduction, describes some knowledge and concepts about the ion imaging, photoionizaiton and photodissociation of molecules etc in brief, respectively. In chapter two, experimental apparatus, the structure and power of the atomic and molecular beamline(U14-A) and TPEPICO-imaging apparatus are introduced, in addition to some knowledge about synchrotron radiation.In chapter three, the dissociation dynamics of NO+ at c 3Π(v’=0) state is studiedby the TPEPICO-imaging technique. The relations between velocity in CM coordinates and MPCM coordinates, TOF and displacement in the velocity map image of fragment ions are derived using vector addition