石墨烯及氧化石墨烯功能分离膜的研究进展和应用.docxVIP

华东理工大学2015—2016学年第一学期《功能性材料科学》课程论文2016.04班级M152 学号名 孙祈安开课学院化学与分子工程学院任课教师陈峰成绩________论文题目：石墨烯及氧化石墨烯功能分离膜的研究进展和应用论文要求：（1）某种功能性材料的研究进展及应用；（2）要求是2015年以后的最新成果。教师评语：教师签字：年月日石墨烯及氧化石墨烯功能分离膜的研究进展和应用摘要：石墨烯及氧化石墨烯由于其独有的性质在分离膜领域引起广泛关注。本文综合分析了石墨烯及氧化石墨烯在分离膜改性方面的几种典型应用，即共混膜、多孔石墨烯膜和层状排列氧化石墨烯膜，并结合其制备方法、效能和作用机理进行阐述。结果表明，层薄和机械性能强的完美结合使石墨烯可以通过打孔形成分离性能较好的多孔石墨烯膜，但是制备大片石墨烯的难度和不成熟的打孔技术限制了其进一步发展；而层状排列的氧化石墨烯膜可充分发挥氧化石墨烯材料的特性，以层间间距作为主要运输通道有利于充分发挥氧化石墨烯高输运速率的优点和高选择性的特性，为开创下一代高通量、高选择性、强抗污染性的高性能分离膜提供了重要思路。关键词 石墨烯 氧化石墨烯 分离膜 膜性能 层状排列氧化石墨烯膜。Abstract: Graphene and graphene oxide(GO) have attracted much attention on separation membrane due to their unique properties. In this paper, we review the membrane modification methods by graphene and GO, including membrane blending with GO, nanoporous graphene membrane and layered GO membrane, and comprehensively analyze the performances and mechanisms of these modified membranes. The results show that: nanoporous graphene membrane has good separation performances because of graphenes high mechanical strength，atomic thickness and ability to support subnanometre pores, but it is challenging to manufacture large graphene with maintaining the structural integrity and control the pore size and pore distribution; the particular properties of GO get the full play in layered GO membranes, which achieve high water flux mainly because the non-oxidized region of GO with nearly frictionless surface promotes the extremely fast flow of water molecules, and obtains high rejection because of rejecting unwanted solutes. Accordingly, layered GO membrane will be thought as a promising membrane separation technology to obtain fine performances of high permeability, selectivity and anti-fouling ability．Key words: graphene; graphene oxide; separation membrane; membrane performance; layered GO membrane发展石墨烯功能分离膜，使其具有高效过滤与分离液相中不同分子和离子的能力对于一系列环境工程应用极其重要。功能分离膜的设计原理包括空间位阻效应、静电相互作用和化学相互作用。由氧化石墨烯(grapheneoxide，GO)微片堆叠而成的层状薄膜可将以上三种分离原理集于一身，在功能分离膜的制备与应用领域极具优势。例如，GO表面电离含氧官能团与离子产生静电