左旋聚乳酸聚己内酯在取向聚乙烯基底上的附生结晶行为研究-材料工程专业论文.docxVIP

北京化工大学硕士学位论文片晶与PE片晶取向一致。PLLA在PE膜上附生冷结晶，PLLA片晶沿两个方向取向，夹角约为550，但绝大部分PLLA分子链与PE分子链垂直。3．进一步研究发现PLLA／PCL共混薄膜在PE基底上的附生结晶行为由共混比及聚合物的类型决定。少量PCL组分的引入便会明显抑制PLLA的附生结晶，这种抑制作用随PCL组分含量增多逐渐明显。当PCL组分含量达到30％及以上时，PLLA在取向PE膜上的附生结晶行为难以发生。而少量PLLA组分的引入则不能显著改变PCL的附生结晶行为。当PLLA组分含量达到50％时，PCL仍然能够在取向PE基底上发生附生结晶。关键词：左旋聚乳酸，聚(￡一己内酯)，共混，冷结晶，PE薄膜，附生结目日日万方数据ABSTRACTEPITAⅪALCRYSTALLIZATIONBEHAVIoRRESEARCHOFPOLY(L-LACTICACID)／POLY(￡-CAPROLACTONE)ONoRIENTEDPOLYETHYLENESUBSTRATEABSTRACTEpitaxialcrystallizationisaneffectivemeanstocontrolthemicrostructuresofpolymermaterials．Epitaxialcrystallizationbehaviorofpurepolymerhasbeenstudiedbymanymaterialresearchers．Ontheotherhand，blendingisaveryconvenientwaytodevelopnewmaterials，whichcancombineexcellentpropertiesofeverycomponent．WehavestudiedPoly(L．1acticacid)／Poly(￡．caprolactone)blends’propertiesandepitaxialcrystallizationonthehighlyorientedpolyethylenesubstrate，aswellasthemutualinfluenceofthecomponentswhentheblendsarecrystallizinginducedbyPEfilms．1．PLLA／PCLblendsareimmiscible．PCLsthermalstabilityisbetterthanPLLAandtwo．stepthermaldegradationisobservedbyTGA．Withthestudyof6：4，5：5，4：6ofblendsamples，PLLAcomponentturnsintothecontinuousphasefromthedispersedphase，whichmeansphaseinversionoccurs．PLLA／PCLblendsarecharacterizedbyXRDandwehavefound万方数据北京化工大学硕士学位论文PLLAcomponentintheblendsalwaysgeneratesO【formcrystalat120Cregardlessofmeltcrystallizationorcoldcrystallization．2．PEfilmishomemadeandusedtOintroducePLLA／PCLblends’Epitaxialcrystallization．PLLAandPCLarehi曲lyorientedonthePEsubstrateandPEfilmshowstrongheterogeneousnucleationabilityforPLLAandPCL．EpitaxialcrystallizationofPCLonPEfilmtakesplacewithitsmolecularchainsparalleltothePEmolecularchains．EpitaxialcoldcrystallizationofPLLAoccurswithitslamellaeorientedintwodirections．Theangleismeasuredasapproximately55。．WhilemostmolecularchainsofPLLAareverticaltothemolecularchainsofPE．3·FurtherresearchshowedthatsmallamountsofPCLcomponentsinhibittheepitaxialcoldcrystallizationofPLLAcomponentssignificantly．IncreasingcontentofPCLleadst