LASER fl#250;rlj#243;mun jo#240;s - hi激光FL与# 250；RLJ与# 243；门乔与# 240；S -嗨.pptVIP

LASER Induced Fluorescence of Iodine Eelisefnafr?ei 5 – 30. mars 2006 ómar Freyr Sigurbj?rnsson Introduction Iodine is the heaviest common halogen and exists as a solid at room temperature in sublimation equilibrium with its vapor. Its vapor has the appearance of a violet gas, indicating a visible absorption. This absorption corresponds to a spin-forbidden transition from the lowest vibrational levels of the singlet electronic ground state to high vibrational levels of a triplet excited state. B 3P0+u ? X 1Sg+ By laser excitation, the reverse process of fluorescence is studied The experimental setup Experimental Iodine crystals were inserted inside the fluorescence cell and the cell was then vacuated and heated The monochromator was set to a wavelength of 630 nm and slidt width of 2000 mm for the indirect absorption measurement by scanning the Dye-Laser and recording the amount of fluorescence The fluorescence spectra was then recorded by scanning the monochromator 1 nm/min and slit width of 500 mm for a fixed Laser excitation wavelength Getting a strong signal was difficult and the slit width could not be smaller, resulting in lower resolution Optimally the scanning speed should be slower Iodine absorption spectrum Iodine absorption spectrum Rotational structure is observed due to the vibrational transition v’=16 ? v’’=2 (B ? X) as determined by the UV/VIS absorption spectrum recorded and assigned in an experiment performed in Physical Chemistry 2 Laser wavelength of 17010,3 cm-1 (587,88 nm) is selected to excite iodine molecules to the specific rotational and vibrational state, then the fluorescence to the ground state vibrational levels is recorded Iodine fluorescence spectra The expected Iodine fluorescence spectra should have peaks corresponding to different vibrational levels of the ground state Also, each vibrational peak should be rotationally split in two due to the fact that for each transition, the selection rule DJ= ± 1 applies Recorded Iodin