注塑级硬质聚氯乙烯复合材料的制备、结构与性能研究-材料加工工程专业论文.docx

ABSTRACTABSTRACTImpr0V堍也e妣d Value of rigid polyv埘lcMoride(PVC)n眈rials throughblendillg aIld enginee血g plays a伊eat role in stiHmlatiI培me deVelopment of PVC i11她姆．The present p印er prepared 11igh-pe响衄anCe rigid PVC blends and‘PvC composi伧s by llSmg e)【缸usion a11d坷eCtion．111e f10m“a，processiI培，s仃ucn聆aIldproperties of吐le rigid PVC blends and PVC composites were hⅣestigated．11le硼粼of也e processing agen『cS 0n me pr叩enies of ri西d iIljection InoldedPVC w笛probed by璐通g or吐1090r试experiInental desi盟and吐1en吐le e毹ct ofmo啊l—phtMate(DOP)on龇propenies of PVc／a唧10ni锄e-bu伽iene一啊rene 0蛆S)cop01ymer blend w觞inVeStig砷ed by nle siIlgle f．actor锄alysis．The reSuns showed也at恤addition of DOP would lead a decreaSe iIl咖aCt s仃eng电distortion tempera：t11re， i11itiation dec0II】【position tempera：ture(乃力，弱well嬲an iIlcreaLse iIl让屺丘aCture Strain 锄d the tempe船：ture of nle nlax decomposition rate(Z-幽曲．In additio玛t：he el锄缸cmod_ulus，tensile蜘g也，dy删c Storage modldllS and t：he secon‘laD，仃a11Sitiontelnper绷鹏如pp_ed firStly a11d t11en iIlcreaSed谢m me contem of DOP．硒gid PVC恤S blendS were prepared lls吨画ection molm昏Morphologicalobsen，a垃on indicarted也at t11ere e)【iS钯d a咖ical SkjIl-core鼬rIlcture in nle i1巧ection—molded bars aIld也e站r血-core鼬ructure w笛q啪titatiVe觚alyzed．For nle core part of the speCiIlleIlS，也e spheml沁-shaped ABS p枷cles weIrc印pro)【i】吐ately homogeneously dispersed ill吐le ma灯i)【锄d me di锄eter(力mged丘Dm O．1 7脚【n t0 0．20胛谢m硫辩嬲啦ABS con：tent舶m 4 phr t0 28 phL G00d compatibil畸between PVC and SAN w鹊aSsi盟ed accordillg t0 me umque臼彻sition of nle PVc／SAN rigidphase，砌ch a110wed buildiIlg s仃0Ilg imer‰ial adllesion b咖e％也e PVC ma廿叔and也eABSp枷cles．Illcorporation of ABS led t0 a decrea∞in yield s吮ng吐l aIld tellSile S仃eng电bm improVed馏1Sile ene增，锄d inlpact toughness．F“te element觚alysis(FEA)model w嬲co血IuCted baSiIlg on the仃{msmission elec们n microscopy(TEM)Inorph0109y锄d tlle mat耐al parameters f．0r aCC0umiIlg f．0r ttle mecllallical propenies趾d位lIctl】reHABSTRACTbehavlor M也e blend aS a function of comem锄d orientation of ABS panicles．‘I。h