半焦催化松木锯末热解实验分析-experimental analysis on pyrolysis of pine sawdust catalyzed by semicoke.docxVIP

摘要能源是人类活动的基础，人类社会的发展需要不断使用优质能源和先进能源技 术。目前全球正面临着新兴国家经济高速发展、发达国家能耗高居不下和一次性能 源资源短缺的严重问题，因此，提高能源效率、改善能源结构、寻求多元化的能量 来源已经成为人们的共识。生物质能由于其来源广泛，并且具有减少对化石燃料的 依赖和减少温室气体排放的双重作用，可在环保的基础上实现对化石燃料的可持续 发展替代而成为研究的热点。本文选用松木热解半焦为研究对象，利用小型管式固定床反应器，考察了不同 反应温度和CO2分压条件下半焦CO2的反应活性，并建立了反应动力学模型。发现反 应温度越高，气化剂中CO2分压越大，半焦的反应活性越高；不同反应温度下未反应 缩芯模型的拟合效果整体上比混合模型好，但当温度＞850 ℃时，半焦与CO2的反应 行为有向混合模型转变的趋势；两种模型的反应速率常数都随着温度和CO2分压的升 高而变大。选用松木锯末为热解实验原料，同时采用松木半焦作催化剂进行了生物质催化 热解实验研究，主要考察了热解温度、半焦添加量、半焦粒径和原料含水率对热解 气成分的影响。实验结果表明：随着温度的升高，热解气中 H2 和 CO 的含量逐渐增 加，二者含量之和最大可达 78.46%，CO2 的含量逐渐减少至 9.99%；减小半焦粒径， H2、CO 有所增长，CH4、CO2 略有减少；原料干燥后 H2+CO 的总含量降低了 7.39%， CO/CO2 比值降低至 3.18。实验条件下得到的最优热解气中 H2+CO 的含量为 85.34%， CO2 的含量为 4.40%。此外还对半焦催化剂使用寿命进行了初步的评估。关键词：生物质能；催化热解；生物质半焦；动力学AbstractEnergy is the material foundation of human activities. The development of human society cannot live without superior energy and the application of advanced energy technology. We are now suffering several serious energy problems, such as rapid economic growth in emerging countries, high energy consumption in developed countries and short supply of one-time energy resource, so how to improve energy efficiency, how to improve the energy structure and how to seek diversification of energy sources have become the consensus of the world. Biomass is abundant, and it can play a dual role by also reducing our reliance on fossil fuels and cutting greenhouse gas emissions, so it will become the focus of further study.The research on reactivity of biomass char with CO2 was studied in a lab-scale fixed bed, mainly investigating the influence of different temperatures and CO2 pressures, and the Unreacted Shrinking Core Model(SCM) and the Hybrid Model(HM) were used to study of reaction kinetic processes. The results indicated that biomass reactive faster with higher temperature and partial pressure of CO2, and that the SCM reflected more realistically than the HM both in different temperature and different CO2 pressure, but what we should notice was that the kinet