苯催化加氢制备环己烷工艺及催化剂改性分析-preparation of cyclohexane by catalytic hydrogenation of benzene and analysis of catalyst modification.docxVIP

?勺/Ill一--一一←一一一一一一一本原旦!牛运区I_:J贞g尘豆l监立一-一一一一一一一一一一-催化苯转化率为57.17%，P-Ni/Ti02催化剂为25.10%，Ni在载体表面均匀分散，可显著提高催化剂活性;但过量的磷酸改性，因在载体上生成了NiO结晶体，反而会造成活性的降低。(5)选取P-l%、Ni-lO%的p-Ni/y-^1203催化剂，考察了其制备过程中焰烧温度对活性的影响。实验结果表明:在熔烧温度350-600.C范罔内，450C时的催化苯转化率最佳，可达57.17%。关键词:环己炕，苯，气相催化，磷酸改性，助剂太原理工大学硕士研究生常付论文STUDYONTECHNOLOGYOFBEN乙ENEHYDROGENATIONTOCYCLOHEXANEANDCATALYSTMODIFIEDABSTRACTAsanorganicsolvent，organicrawmaterialandacompositionofthesynthesisprocessofpolyamidefiberproducts，CyclohexanecanbegainedbyBcnzenchydrogenationandoiIfractionsrecovery.WiththerequicmentsofCyclohexaneincreasingrapidly，oilfractionsrecoverycannotafforditinquantityandquality，soBenzenebydrogenationhasbeenthemainmethodtoCyclohexane.Inpacewiththeprogressofrefiningcoalcok.ingproducts，ithasbeenanimportantstudyfìeldforBenzenerefinedformcokingcrudeBenzenetoCyclohexane.Currently，theactivecomponenlinBenzenehydrogenalion.::atalystsismainlynoblemetal.Thecommonmethodofimprovingcatalyticactivityis10increasetheloading，whichleadstoincreaselheconsurnplionofnoblemctalandreducccconomicbenefit.Inorder10rcduceprocesscost，slrengthenproductioncapacityandthereasonableapplicationofnaturalre$ourcesintheficldofcoaJ-cokingrefinedprocess，itisimperativetodcvelopakindofeconomicalandpracticalbenzenehydrogenationcatalystwithlowerloading.-lurV太原理l人学硕士明究生学位i文1nthispaper，thecatalystswerepreparedusingvolumetricimmersionmethodwhichwasusedinbenzenehydrogenationbyintegralcyclohexanereactor.ThepropertieswerecharacterizedbyXRD，TPRandIRetc.TakentheconversionrateandselectivityofCyclohexaneastheevaluationstandardofcatalysts，thebenzenehydrogenationcatalyticprocessandcataly创sofpr巳paratingCyclohexanewerestudi巳dinlh巳?Sp巳ctsofr巳:.1ctlonop巳ratingconditiol1soptimization，supportselectionandadditives，supportandpreparationprocessconditions.Themainconclusionswere:(1)WithNi(N03)2precursor，Ni/y-AI20}(loadingmasspercentis:10%，Ni-30%)catalystwassynthesized.Theeffectofreactiontemperature(T)，Hydrogen-?enzenemoleratio(H2/C6H6)，Benzeneliquidspacevelocity(VLsp)andreactionpresslIr巳(