吡嗪2356四甲酸 44联吡啶桥联的配合物的合成 结构及性质研究-study on the synthesis structure and properties of pyrazin2356 tetracarboxylic acid 44 bipyridine bridged complexes.docx

ABSTRACT4，4飞bipyridinehastwocoordinationsitesanditsagoodbridgingIigandswithnonbranchedchainandsmallsterichindrance.Thetwopyridineringsaroundthecarbon-carbonbondcanbeanyrotation，soitcanfonnavarietyofspatialstructureofthecomplex.Pyrazine唰2，3，5，6-tetracarboxylicacidhasrichcoordinationsitesandagreatlysymmetricalstruc阳rewithahighdegreeofrigidity.ByusingPyrazine-2，3，5，6-tetracarboxylicacidand4，4-bipyridineasmixedbridgingligand，novel10chains，20framework，30networkcomplexeshavebeensuccessfullysynthesized.Furthermore，thenovelwatercluster，thestructureandthecoordinationmodeofthecomplexarealsoexplainedindetailed.InthisstudiesfourcomplexeswithH4pztcand4，4-bipyridine{[CU3(pztc)z(Hbpy)z(bpy)(H20)6]6.5H20}n(1)，([Zn3(Pztc)z(Hbpy)z(bpy)(H20)4]7H20}n(2)，{A(bpY)4(PztC)}n(3)，{Ag2(bpY)I.5(pztc)o.s}n(4)(pztc=Pyrazine-2，3，5，6-tetracarboxylicacid，bpy=4，4bipyridine)havebeensynthesizedandcharacterizedbythennogravimetric(TG)analysis，IRspectrum，Fluorescencespectrum..UVabsorptionspectrum，andsingle-crystalX-raydiffraction.Complex1isa10chainstructurelikeafishbone，crystallizedintheOrthorhombicspacegroupPnna.Complexes2isa3DnetworkstructurecrystallizedintheOrthorhombicspacegroupPcca.Metalionsareallsix幽coordinatedintheComplex1andComplex2，exhibitingdistortedoctahedralcoordinationgeometrγ.ThroughthenormalcoordinationbondsComplex2fonnthe30networkstructure.Complex3crystallizesintheOrthorhombicspacegroupIbcaandformsthe20layeredstructure.Complex4CIγstallizesintheTriclinicspacegroupPlwhichfonns3Dnetworkstructure.SilverionsintheComplex3andComplex4areallthree嗣coordinated，，随exhibiting丁riangleplaneror下shapedcoordinationgeomet巧人Complex4formedthe30networkstruc阳rebytheweakbondinglikemetal嗣metalandmetal-oxygenbonds.市The(H20)4waterclusterand(H20)1Owaterclusterarepresentedin1and2respectively.KEYWORDS:Pyrazine-2，3，5，6-tetracarboxylicacid，4，4-bipyridine，complex，watercluster.目录第一章前言.1.1日比嚓-2，3，5，6-四申酸的研究现状………....………....…..............................11.24，4-联毗昵配体的研究现状.................................…............…….......