钴 镍 铜基配合物的合成 晶体结构及性质分析-synthesis crystal structure and properties analysis of cobalt - nickel - copper complex.docx

桂桂 林理工 大学 硕士学 位论 文万方数据万方数据AbstractThe chemistry of materials is a frontier field of research. The possibility of designing, modeling and synthesizing solids with predefined aggregation of ions or molecules is attracting an increasing number of scientists. Therefore, with a variety of organic ligands directed to build cluster complexes, explore their assembly law, the structure-activity relationship has become one of the forefront challenging topics in the field of functional materials today.In this thesis, we selected (2-hydroxy-4-methoxyphenyl)(phenyl)methanone, 3-amino-2-hydroxyacetophenone and three kinds of schiff base as the ligand. 12 complexes have been directional constructed and characterized by IR, UV spectra, elemental analyses, variable-temperature and variable-field magnetic measurements and fluorescence Properties, while their spatial structure and coordination were discussed. This thesis is divided into five chapters.In the first chapter, the main facets, several recent topics and the role of metal atoms of the crystal engineering are systemically introduced, as well as the research significance and the process of this thesis.In the second chapter, three cobalt-based clusters and one nickel-based cluster have been synthesized with (2-hydroxy-4-methoxyphenyl)(phenyl)methanone and contributed by displacing the auxiliary ligand, counter anion, and so on. The structural analysis reveals that all four clusters are defined as trinuclear clusterswith three cobalt/nickel atoms Co???Co???Co（ Ni???Ni???Ni） linked in line. Allclusters are neatly arranged and stacked into three-dimensional structure under the joint action of the electrostatic attraction, van der waals and weak intermolecular force. Magnet studies indicated that the ferromagnetic interaction between cobalt/nickel ions in the clusters.In the third chapter, two tetranuclear nickel complexes have been solvothermally synthesized with 3-amino-2-hydroxyacetophenone and contributed by regulating